Experimental study of a diffusion-controlled reaction involving a chain molecule with terminal reactive sites

Experimental study of a diffusion-controlled reaction involving a chain molecule with terminal... Diffusion-controlled reaction of electron transfer from diphenylsilane radical anions to the series of α- and α,ω-bromoalkanes with alkane chain length up to 18 atoms has been studied in n-dodecane solutions. At room temperature, reaction rate constants have been determined and corresponding reaction radii have been evaluated. It has been shown that a not-too-long chain molecule, which contains two terminal reaction sites and participates in the diffusion-controlled reaction, may be considered as a rapidly rotating pair of reacting sinks with a distance between their centers equal to the mean-square end-to-end distance of the molecule. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Experimental study of a diffusion-controlled reaction involving a chain molecule with terminal reactive sites

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Publisher
Springer Netherlands
Copyright
Copyright © 2009 by Springer Science+Business Media BV
Subject
Chemistry; Inorganic Chemistry ; Physical Chemistry ; Catalysis
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-009-0055-3
Publisher site
See Article on Publisher Site

References

  • Dissociative electron transfer between arene radical anions and halogenoalkanes: a pulse radiolysis study
    Grimshaw, J; Langan, JR; Salmon, GA
  • Time-resolved electric field effects in recombination fluorescence as a method of studying primary radiation-chemical processes
    Borovkov, VI; Anishchik, SV; Anisimov, OA

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