Experimental study of a diffusion-controlled reaction involving a chain molecule with terminal reactive sites

Experimental study of a diffusion-controlled reaction involving a chain molecule with terminal... Diffusion-controlled reaction of electron transfer from diphenylsilane radical anions to the series of α- and α,ω-bromoalkanes with alkane chain length up to 18 atoms has been studied in n-dodecane solutions. At room temperature, reaction rate constants have been determined and corresponding reaction radii have been evaluated. It has been shown that a not-too-long chain molecule, which contains two terminal reaction sites and participates in the diffusion-controlled reaction, may be considered as a rapidly rotating pair of reacting sinks with a distance between their centers equal to the mean-square end-to-end distance of the molecule. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Experimental study of a diffusion-controlled reaction involving a chain molecule with terminal reactive sites

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Springer Netherlands
Copyright © 2009 by Springer Science+Business Media BV
Chemistry; Inorganic Chemistry ; Physical Chemistry ; Catalysis
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