EPR studies of spin-spin interactions between Cu(II) centers in dimeric, hexameric and homo- and heteronuclear tetrameric complexes

EPR studies of spin-spin interactions between Cu(II) centers in dimeric, hexameric and homo- and... Applications of conventional (X-band), High-Field and High-Frequency EPR to study the nature of exchange interactions between Cu(II) centres in different homo- and hetronuclear systems are reviewed. The fine structure EPR spectra have been observed and analyzed in terms of spin-Hamiltonian parameters corresponding to S ≥ 1 for different [Cu2(β-alanine)4Cl2]Cl2·H2O dimeric complexes present in one unit cell, Cu(II) dimers possessing different conformations, dimeric species formed between Cu(II) ions and polyfunctional ligand in solution, Cu-Zn-Cu-Zn and Cu-Co-Cu-Co tetrameric heterometallomacrocycles, Cu4O4 cubane-like tetramers and for the chain Cu(II) hexamer. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

EPR studies of spin-spin interactions between Cu(II) centers in dimeric, hexameric and homo- and heteronuclear tetrameric complexes

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Publisher
Brill Academic Publishers
Copyright
Copyright © 2007 by VSP
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856707782169381
Publisher site
See Article on Publisher Site

Abstract

Applications of conventional (X-band), High-Field and High-Frequency EPR to study the nature of exchange interactions between Cu(II) centres in different homo- and hetronuclear systems are reviewed. The fine structure EPR spectra have been observed and analyzed in terms of spin-Hamiltonian parameters corresponding to S ≥ 1 for different [Cu2(β-alanine)4Cl2]Cl2·H2O dimeric complexes present in one unit cell, Cu(II) dimers possessing different conformations, dimeric species formed between Cu(II) ions and polyfunctional ligand in solution, Cu-Zn-Cu-Zn and Cu-Co-Cu-Co tetrameric heterometallomacrocycles, Cu4O4 cubane-like tetramers and for the chain Cu(II) hexamer.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jan 1, 2007

References

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