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L. Marosi, G. Cox, A. Tenten, H. Hibst (2000)
In Situ XRD Investigations of Heteropolyacid Catalysts in the Methacrolein to Methacrylic Acid Oxidation Reaction: Structural Changes during the Activation/Deactivation ProcessJournal of Catalysis, 194
Suzhi Li, Junwei Zhao, P. Ma, Juana Du, J. Niu, Jingping Wang (2009)
Rare sandwich-type polyoxomolybdates constructed from Di-/tetra-nuclear transition-metal clusters and trivacant keggin germanomolybdate fragments.Inorganic chemistry, 48 20
J. Jankowiak, M. Barteau (2005)
Ethylene epoxidation over silver and copper-silver bimetallic catalysts: I. Kinetics and selectivityJournal of Catalysis, 236
W. Knoth, P. Domaille, R. Harlow (1986)
Heteropolyanions of the types M3(W9PO34)212- and MM'M"(W9PO34)212-: novel coordination of nitrate and nitriteInorganic Chemistry, 25
L. Hatch, S. Matar (1981)
From Hydrocarbons to Petrochemicals
L. Marosi, C. Areán (2003)
Catalytic performance of Csx(NH4)yHzPMo12O40 and related heteropolyacids in the methacrolein to methacrylic acid conversion: in situ structural study of the formation and stability of the catalytically active speciesJournal of Catalysis, 213
M. Haruta, B. Uphade, S. Tsubota, A. Miyamoto (1998)
Selective oxidation of propylene over gold deposited on titanium-based oxidesResearch on Chemical Intermediates, 24
Yong Ding, B. Ma, Q. Gao, Guixian Li, Liang Yan, J. Suo (2005)
A spectroscopic study on the 12-heteropolyacids of molybdenum and tungsten (H3PMo12−nWnO40) combined with cetylpyridinium bromide in the epoxidation of cyclopenteneJournal of Molecular Catalysis A-chemical, 230
C. Hill (2007)
Progress and challenges in polyoxometalate-based catalysis and catalytic materials chemistryJournal of Molecular Catalysis A-chemical, 262
A. Sulimov, S. Danov, A. Ovcharova, A. Ovcharov, V. Flid (2014)
Kinetics of allyl chloride epoxidation with hydrogen peroxide catalyzed by extruded titanium silicaliteKinetics and Catalysis, 55
Ruipeng Ren, Rui-Xin Xi, X. Pang, Yongkang Lü (2011)
DFT study on the selective oxidation of vinyl chloride on different metal surfacesJournal of Natural Gas Chemistry, 20
Guixian Li, Yong Ding, Jianming Wang, Xiaolai Wang, J. Suo (2007)
New progress of Keggin and Wells–Dawson type polyoxometalates catalyze acid and oxidative reactionsJournal of Molecular Catalysis A-chemical, 262
Lu Liu, X. Ye, J. Bozell (2012)
A comparative review of petroleum-based and bio-based acrolein production.ChemSusChem, 5 7
C. Beck, T. Mallát, T. Bürgi, A. Baiker (2001)
Nature of Active Sites in Sol–Gel TiO2–SiO2 Epoxidation CatalystsJournal of Catalysis, 204
A. Wróblewska, E. Makuch (2014)
Regeneration of the Ti-SBA-15 Catalyst Used in the Process of Allyl Alcohol Epoxidation with Hydrogen PeroxideJournal of Advanced Oxidation Technologies, 17
Toshio Hayashi, Koji Tanaka, M. Haruta (1998)
Selective Vapor-Phase Epoxidation of Propylene over Au/TiO2Catalysts in the Presence of Oxygen and HydrogenJournal of Catalysis, 178
J. Niu, X. You, Jingping Wang (1996)
Preparation, characterization and magnetic properties of disubstituted ternary heteropolyoxometalates [TBA]3Hn[PW9MoM2-O38(H2O)2]· 3C3H6O(TBA = tetrabutylammonium, M = transition metal)Transition Metal Chemistry, 21
Jinjuan Xue, Aili Wang, Hengbo Yin, Jingbo Wang, Dongzhi Zhang, Weiguang Chen, Longbao Yu, Tingshun Jiang (2010)
Oxidation of cyclopentene catalyzed by phosphotungstic quaternary ammonium salt catalystsJournal of Industrial and Engineering Chemistry, 16
V. Choudhary, R. Jha, P. Jana (2008)
Selective epoxidation of styrene to styrene oxide by TBHP using simple transition metal oxides (NiO, CoO or MoO3) as highly active environmentally-friendly catalystCatalysis Communications, 10
L. Espinal, S. Suib, J. Rusling (2004)
Electrochemical catalysis of styrene epoxidation with films of MnO(2) nanoparticles and H(2)O(2).Journal of the American Chemical Society, 126 24
R. Kirk, D. Othmer (1998)
Encyclopedia of chemical technology
P. Villabrille, G. Romanelli, P. Vázquez, C. Caceres (2004)
Vanadium-substituted Keggin heteropolycompounds as catalysts for ecofriendly liquid phase oxidation of 2,6-dimethylphenol to 2,6-dimethyl-1,4-benzoquinoneApplied Catalysis A-general, 270
J. Niu, Jingping Wang, X. You, T. Mak, Zhongyuan Zhou (1996)
Transition metal disubstituted ternary heteropolyoxometallates: Synthesis, characterization, crystal structure and magnetic propertiesPolyhedron, 15
J. Monnier, J. Stavinoha, Robin Minga (2004)
Stability and distribution of cesium in Cs-promoted silver catalysts used for butadiene epoxidationJournal of Catalysis, 226
M. Clerici, P. Ingallina (1993)
Epoxidation of Lower Olefins with Hydrogen Peroxide and Titanium SilicaliteJournal of Catalysis, 140
P. Domaille, G. Watunya (1986)
Synthesis and tungsten-183 NMR characterization of vanadium-substituted polyoxometalates based on B-type tungstophosphate PW9O349-precursorsInorganic Chemistry, 25
Heesoo Kim, J. Jung, D. Park, S. Baeck, I. Song (2007)
Preparation of H5PMo10V2O40 (PMo10V2) catalyst immobilized on nitrogen-containing mesoporous carbon (N-MC) and its application to the methacrolein oxidationApplied Catalysis A-general, 320
Y. Ishii, K. Yamawaki, T. Ura, H. Yamada, Tsutomu Yoshida, M. Ogawa (1988)
Hydrogen peroxide oxidation catalyzed by heteropoly acids combined with cetylpyridinium chloride. Epoxidation of olefins and allylic alcohols, ketonization of alcohols and diols, and oxidative cleavage of 1,2-diols and olefinsJournal of Organic Chemistry, 53
W. Archer (1996)
Industrial solvents handbook
T. Okuhara, N. Mizuno, M. Misono (2001)
Catalysis by heteropoly compounds—recent developmentsApplied Catalysis A-general, 222
C. Hill, D. Bouchard (1985)
Catalytic photochemical dehydrogenation of organic substrates by polyoxometalatesJournal of the American Chemical Society, 107
N. Mizuno, Keigo Kamata (2011)
Catalytic oxidation of hydrocarbons with hydrogen peroxide by vanadium-based polyoxometalatesCoordination Chemistry Reviews, 255
Mitsuru Kanno, T. Yasukawa, W. Ninomiya, Ken Ooyachi, Y. Kamiya (2010)
Catalytic oxidation of methacrolein to methacrylic acid over silica-supported 11-molybdo-1-vanadophosphoric acid with different heteropolyacid loadingsJournal of Catalysis, 273
А ЧернышковаФ, В МушенкоД, А БландинаЛ (1974)
金属ゼオライト触媒上でのオレフィンのα-オキシドの水素化:第1級アルコールの製造, 14
S. Krijnen, P. Sánchez, B. Jakobs, V. Hooff (1999)
A controlled post-synthesis route to well-defined and active titanium Beta epoxidation catalystsMicroporous and Mesoporous Materials, 31
Miao Sun, Jizhen Zhang, Chuanjing Cao, Qinghong Zhang, Ye Wang, H. Wan (2008)
Significant effect of acidity on catalytic behaviors of Cs-substituted polyoxometalates for oxidative dehydrogenation of propaneApplied Catalysis A-general, 349
(1974)
Epoxidation of 1-butene to 1,2-butene oxide
L. Kuznetsova, N. Kuznetsova, R. Maksimovskaya, O. Koshcheeva, V. Utkin (2013)
Catalytic properties of heteropoly compounds in 1,3-butadiene oxidation with hydrogen peroxideKinetics and Catalysis, 54
Ruipu Wang, Xinwen Guo, Xiangsheng Wang, J. Hao (2003)
Propylene Epoxidation Over Silver Supported on Titanium Silicalite ZeoliteCatalysis Letters, 90
H. Böhnke, J. Gaube, J. Petzoldt (2006)
Selective oxidation of methacrolein towards methacrylic acid on mixed oxide (Mo, V, W) catalysts. Part 2. Variation of catalyst composition and comparison with acrolein oxidationIndustrial & Engineering Chemistry Research, 45
A series of transitional metal disubstituted ternary heteropoly quaternary ammonium salts, [TPA]4H3[PW7Mo3M2O38(H2O)2] (M = Mn, Co, Ni, Cu), were prepared by the reaction of the anion PW6Mo3O34 9− and the corresponding salts of the transitional metal in water, characterized by FI-IR, UV–Vis, XRD and TGA spectra, and appied to the epoxidation of 1-butene to 1,2-butene oxide (BO). The influences of temperature, reaction time, H2O2 concentration and catalyst concentration on the epoxidation of 1-butene were studied in the acetonitrile/hydrogen peroxide catalytic system. The variation ranges of these parameters ensuring a high H2O2 conversion and high selectivity of BO were established. It can be observed that the catalytic activity decreases in the order PWMoMn > PWMoCo > PWMoNi > PWMoCu. The best conversion of H2O2 and selectivity toward BO were achieved under optimized conditions: reaction time = 2 h, reaction temperature = 50 °C, H2O2 concentration = 0.5 mol/L and a catalyst concentration of 2.5 g/L. In particular, the catalyst PWMoMn is the most active one for epoxidation of 1-butene to BO (selectivity of BO up to 97.6 %).
Research on Chemical Intermediates – Springer Journals
Published: Feb 7, 2015
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