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(1061)
Chem
- Publisher
- Springer Journals
- Copyright
- Copyright © 2018 by The Minerals, Metals & Materials Society
- Subject
- Materials Science; Optical and Electronic Materials; Characterization and Evaluation of Materials; Electronics and Microelectronics, Instrumentation; Solid State Physics
- ISSN
- 0361-5235
- eISSN
- 1543-186X
- DOI
- 10.1007/s11664-018-6279-5
- Publisher site
- See Article on Publisher Site
Abstract
Aqueous vitamin C solution has been used as an environment-friendly reducing agent for tuning the thermoelectric properties of p-toluenesulfonate-doped poly(3,4-ethylenedioxythiophene) (PEDOT-Tos) films. The de-doping of the PEDOT-Tos films by aqueous vitamin C solutions led to a decrease in the electrical conductivity of the films. The measured ultraviolet-visible-near-infrared and x-ray photoelectron spectra clearly indicated the reduction in the oxidation level from 37 to 23% when the PEDOT-Tos films were treated with 5% (w/v) aqueous vitamin C solutions. An increase in the Seebeck coefficient was measured, resulting in an increase in the figure-of-merit (ZT). A 42% increase in ZT was determined for the 5% aqueous vitamin C solution-treated PEDOT-Tos films with respect to that of the untreated films.
Journal
Journal of Electronic Materials – Springer Journals
Published: Apr 13, 2018