Access the full text.
Sign up today, get DeepDyve free for 14 days.
Renu Thakur, R. Ranjan (2015)
Oxidative degradation and associated complexation study of citric acid by di-tertiary butyl chromateAsian Journal of Research in Chemistry, 8
S. Sundaram, P. Raghavan (2011)
Chromium -VI Reagents: Synthetic Applications
G. Fowles, R. Matthews, R. Walton (1968)
Studies on co-ordination compounds of silver(II). Part I. Magnetic and spectral properties of complexes with pyridine carboxylic acidsJournal of The Chemical Society A: Inorganic, Physical, Theoretical
Aniruddha Ghosh, R. Saha, K. Mukherjee, P. Sar, Sumanta Ghosh, Susanta Malik, Subhendu Bhattacharyya, Bidyut Saha (2014)
Rate enhancement via micelle encapsulation for room temperature metal catalyzed Ce(IV) oxidation of p-chlorobenzaldehyde to p-chlorobenzoic acid in aqueous medium at atmospheric pressureJournal of Molecular Liquids, 190
F. Fairbrother (1963)
Book reviewA text-book of quantitative inorganic analysis: A. I. Vogel: (including elementary instrumental analysis). 3rd Ed. Longmans, Green, London, 1962. Pp.xxx + 1216 70s.Journal of Inorganic and Nuclear Chemistry, 25
(2008)
Fundamental Concepts of Inorganic Chemistry, vol
(1961)
A Text Book of Quantitative Inorganic Analysis (Pergamon
(2022)
Purification of Laboratory Chemicals
A. Lever, S. Rice (1968)
Inorganic Electronic Spectroscopy
G. Henehan, N. Oppenheimer (1993)
Horse liver alcohol dehydrogenase-catalyzed oxidation of aldehydes: dismutation precedes net production of reduced nicotinamide adenine dinucleotide.Biochemistry, 32 3
Susanta Malik, Monohar Mondal, Aniruddha Ghosh, Sourav De, K. Mahali, S. Bhattacharyya, Bidyut Saha (2016)
Combination of Sodium Dodecylsulfate and 2,2′-Bipyridine for Hundred Fold Rate Enhancement of Chromium(VI) Oxidation of Malonic Acid at Room Temperature: A Greener ApproachJournal of Solution Chemistry, 45
G. Sorella, G. Strukul, A. Scarso (2015)
Recent advances in catalysis in micellar mediaGreen Chemistry, 17
B. Douglas, D. Mcdaniel (1965)
Concepts and Models of Inorganic Chemistry
J. Ferguson (1961)
The ultra-violet absorption spectra of solutions of some copper and nickel complexes—evidence for covalent bindingSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 17
R. Saha, Aniruddha Ghosh, Bidyut Saha (2011)
Micellar catalysis on 1,10-phenanthroline promoted hexavalent chromium oxidation of ethanolJournal of Coordination Chemistry, 64
T. Dwars, E. Paetzold, G. Oehme (2005)
Reactions in micellar systems.Angewandte Chemie, 44 44
(2012)
Inorganic Chemistry, Part-II (Chemical Elements and Their Compounds), 6th edn
J. Mandal, K. Chowdhury, K. Paul, Bidyut Saha (2008)
Kinetics and Mechanism of 2,2’-Bipyridyl Promoted Chromic Acid Oxidation of Ethanol and Propan-1-ol in Aqueous Micellar Media~!2008-08-15~!2008-09-26~!2008-11-14~!The Open Catalysis Journal, 1
(1670)
Asian J
Bidyut Saha, K. Chowdhury, J. Mandal (2008)
Micellar Catalysis on Pentavalent Vanadium Ion Oxidation of D-Sorbitol in Aqueous Acid Media: A Kinetic StudyJournal of Solution Chemistry, 37
R. Carlin (1963)
Electronic spectra of transition metal complexesJournal of Chemical Education, 40
Y. Katre, S. Nayak, D. Sharma, Ajaya Singh (2011)
Kinetic study of oxidation of galactose by N-bromo phthalimide in the presence of cationic micelle in acidic mediumResearch on Chemical Intermediates, 38
L. Funck, T. Ortolano (1968)
Effects of axial ligation on the ligand field spectra of copper(II) .beta.-diketonatesInorganic Chemistry, 7
(2011)
S
Susanta Malik, Aniruddha Ghosh, K. Mukherjee, Bidyut Saha (2014)
Combination of Best Promoter and Micellar Catalyst for Cr(VI) Oxidation of Lactose to Lactobionic Acid in Aqueous Medium at Room TemperatureTenside Surfactants Detergents, 51
Jiaxiang Zhang, Lun Pan, Jun Mo, Jing Gong, Zuo-hua Huang, C. Law (2013)
A shock tube and kinetic modeling study of n-butanal oxidationCombustion and Flame, 160
Z. Khan, Shalu Masan, Raju, Kabir-ud-din (2003)
A mechanistic study of the ethylenediaminetetraacetic acid-, 2,2′-bipyridyl-, and manganese(II)-assisted one-step two- and three-electron oxidation of lactic acid by chromium(VI)Transition Metal Chemistry, 28
Monohar Mondal, Susanta Malik, Ankit Roy, R. Saha, Bidyut Saha (2015)
Modernization of surfactant chemistry in the age of gemini and bio-surfactants: a reviewRSC Advances, 5
P. Day, C. Flint (2011)
Electronic Spectra of Transition Metal Complexes
R. Dutta, R. Ray (1979)
Studies in copper(II) chelates—XI. Picolinato mono(biguanide) copper(II)Journal of Inorganic and Nuclear Chemistry, 41
A recent “Renaissance” has various fields of chemistry exploring processes that are more Earth-friendly One focus is to make kinetic experiments greener by applying modified methodologies for metal mediated oxidation kinetics mean while recycling the used reagents and catalysts after completion in greener aqueous media. Use of surfactants has been established as a green modification to conventional chemical transformation reactions. Here bipyridine, a hetero-aromatic notrogen base was employed as promoter in association with cationic, anionic and non-ionic surfactants for room temperature oxidation of butanal to butyric acid. Results are compared with unpromoted and uncatalysed Cu2+ (aq) oxidation (E 0 Cu 2+ (aq)/ Cu + (aq) = 0.15 V). All the reactions were performed under the pseudo-first-order kinetics at 30 °C. The determined pseudo-first-order rate constant (k obs) and half-life value (t 1/2) of all the reactions indicates that sodium dodecyl sulphate inhibits the reaction rate while N-cetylpyridinium chloride accelerates the same in the titled kinetic experiment. The suitable formal potential in the presence of bipyridine guides the reaction to follow faster kinetics. The yield of the final butyric acid from butanal were found to be satisfactory (see “Yield (approx) of butyric acid in different reaction systems”). The purity of the oxidized product was determined by specific gravity calculation after fractional distillation along with 1H-NMR and FTIR spectroscopic measurements. Formation of micelle in the kinetic study was proved by optical imaging and TEM studies; incorporation of active substrate and reagents in micellar core was found with DLS data.
Research on Chemical Intermediates – Springer Journals
Published: Sep 12, 2016
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.