Electron transfer. 153. Internal electron transfer to bound cobalt(III) induced by hydroxyl radical

Electron transfer. 153. Internal electron transfer to bound cobalt(III) induced by hydroxyl radical Hydroxyl radicals, generated in aqueous solution from Fe2+ and H2O2, react with the formato, glycolato, lactato and mandelato complexes of (NH3)5CoIII, extracting H·, releasing CO2 and inducing the internal reduction of CoIII to Co2+; decomposition of peroxynitrous acid (O=N—OOH) in the presence of these complexes also yields Co2+, indicating partial utilization (15% at 22°C and pH 1) of a path involving OH·. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Electron transfer. 153. Internal electron transfer to bound cobalt(III) induced by hydroxyl radical

Loading next page...
 
/lp/springer_journal/electron-transfer-153-internal-electron-transfer-to-bound-cobalt-iii-dwh6bgkjfK
Publisher
Brill Academic Publishers
Copyright
Copyright © 2003 by VSP 2003
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856703765694291
Publisher site
See Article on Publisher Site

Abstract

Hydroxyl radicals, generated in aqueous solution from Fe2+ and H2O2, react with the formato, glycolato, lactato and mandelato complexes of (NH3)5CoIII, extracting H·, releasing CO2 and inducing the internal reduction of CoIII to Co2+; decomposition of peroxynitrous acid (O=N—OOH) in the presence of these complexes also yields Co2+, indicating partial utilization (15% at 22°C and pH 1) of a path involving OH·.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Oct 17, 2004

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from
Google Scholar,
PubMed
Create lists to
organize your research
Export lists, citations
Read DeepDyve articles
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off