Aqueous solutions of indium(III) undergo 1e− reductions by Sm(II) (E0-1.55 V) and by Yb(II) (−1.05 V), but not by U(III) (−0.52 V). The facile and irreversible reduction, by In+ aq, of Ru(NH3)6 3+ (E0+0.067 V) at reagent concentrations near 10−3 M implies a potential more negative than −0.23 V for In(II,I) and, in conjunction with the known value of −0.44 V for In(III,I), a complementary potential less negative than −0.65 V for In(III,II). These observations, taken together, support le− indium potentials EII,I o−0.2 V and EIII,II 0−0.6 V.
Research on Chemical Intermediates – Springer Journals
Published: Apr 14, 2009
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