Electron transfer. 137. Formal potentials involving indium(II)

Electron transfer. 137. Formal potentials involving indium(II) Aqueous solutions of indium(III) undergo 1e− reductions by Sm(II) (E0-1.55 V) and by Yb(II) (−1.05 V), but not by U(III) (−0.52 V). The facile and irreversible reduction, by In+ aq, of Ru(NH3)6 3+ (E0+0.067 V) at reagent concentrations near 10−3 M implies a potential more negative than −0.23 V for In(II,I) and, in conjunction with the known value of −0.44 V for In(III,I), a complementary potential less negative than −0.65 V for In(III,II). These observations, taken together, support le− indium potentials EII,I o−0.2 V and EIII,II 0−0.6 V. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Electron transfer. 137. Formal potentials involving indium(II)

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Springer Netherlands
Copyright © 1998 by Springer
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
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