The possibility of preparing isonicotinoylisopropylhydrazine by electrochemical reduction of the corresponding hydrazone on stationary solid electrodes (titanium, zirconium, nickel, iron, iron-based alloys) was demonstrated. The electrolysis is performed in the cathodic space of the electrolyzer on solid cathodes in aqueous-alcoholic solutions, with glassy carbon used as anode. The hydrazone electroreduction is performed at the cathodic current density of 0.1–0.5 A dm–2 in the temperature interval 40–70°С for 2–5 h. On electrodes with low overvoltage of hydrogen evolution, the C=N double bonds in isonicotinoylisopropylidenehydrazine relatively readily undergo electrohydrogenation with atomic hydrogen.
Russian Journal of Applied Chemistry – Springer Journals
Published: Dec 23, 2015
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