Electrochemical study of the reduction of Tm(III) ions in a molten NaCl-2CsCl eutectic

Electrochemical study of the reduction of Tm(III) ions in a molten NaCl-2CsCl eutectic Electrochemical behavior of TmCl3 solutions in a NaCl-2CsCl eutectic melt at temperatures of 823–973 K on an inert Mo electrode was studied by cyclic and square-wave voltammetry and the method of electromotive forces. The mechanism of the cathodic process was determined, kinetic parameters of the Tm(III) + e ⇆ Tm(II) reaction were found, and the temperature dependence of the diffusion coefficients of Tm(III) ions was calculated. The conditional standard redox potential for the Tm(III)/Tm(II) pair was measured in the temperature range under study. The basic thermodynamic characteristics of the Tm(III) + e ⇆ Tm(II) redox reaction in a molten NaCl-2CsCl eutectic mixture were determined. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Electrochemical study of the reduction of Tm(III) ions in a molten NaCl-2CsCl eutectic

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SP MAIK Nauka/Interperiodica
Copyright © 2012 by Pleiades Publishing, Ltd.
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
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