Foil 2nm 6nm O=C=O CO Cu Au Keywords Copper · Gold · Alloy · CO reduction · Electrocatalysis · Carbon dioxide · Nanoparticle 1 Introduction Transition metals such as Cu, Ni, Sn, and Fe have long been Electronic supplementary material The online version of this considered as potential catalysts for CO reduction [1–4]. article (https ://doi.org/10.1007/s1080 0-018-1166-6) contains Of the transition metals, Cu [5–7] has been the most heav- supplementary material, which is available to authorized users. ily investigated as it produces hydrocarbons at relatively −2 * John Flake high current densities (~ 5 mA cm ) and Faradaic efficien- email@example.com cies > 60% [6, 8]. Likewise, other noble metals such as Au and Ag are known to produce CO at relatively high current Cain Department of Chemical Engineering, Louisiana State densities and Faradaic efficiencies exceeding 90% [9 , 10]. University, Baton Rouge, LA 70803, USA Vol.:(0123456789) 1 3 436 Journal of Applied Electrochemistry (2018) 48:435–441 In recent years, there has been significant progress in the follow the same linear relationship as pure metals ; so synthesis of well-defined nanoparticles using wet proce - these may offer an opportunity to break the linear scaling in dures such as Brust Schiffrin, Perrault , Martin , or binding energies and alter product
Journal of Applied Electrochemistry – Springer Journals
Published: Feb 19, 2018
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