Electrochemical reduction of CO2 at CuAu nanoparticles: size and alloy effects

Electrochemical reduction of CO2 at CuAu nanoparticles: size and alloy effects Foil 2nm 6nm O=C=O CO Cu Au Keywords Copper · Gold · Alloy · CO reduction · Electrocatalysis · Carbon dioxide · Nanoparticle 1 Introduction Transition metals such as Cu, Ni, Sn, and Fe have long been Electronic supplementary material The online version of this considered as potential catalysts for CO reduction [1–4]. article (https ://doi.org/10.1007/s1080 0-018-1166-6) contains Of the transition metals, Cu [5–7] has been the most heav- supplementary material, which is available to authorized users. ily investigated as it produces hydrocarbons at relatively −2 * John Flake high current densities (~ 5 mA cm ) and Faradaic efficien- johnflake@lsu.edu cies > 60% [6, 8]. Likewise, other noble metals such as Au and Ag are known to produce CO at relatively high current Cain Department of Chemical Engineering, Louisiana State densities and Faradaic efficiencies exceeding 90% [9 , 10]. University, Baton Rouge, LA 70803, USA Vol.:(0123456789) 1 3 436 Journal of Applied Electrochemistry (2018) 48:435–441 In recent years, there has been significant progress in the follow the same linear relationship as pure metals [28]; so synthesis of well-defined nanoparticles using wet proce - these may offer an opportunity to break the linear scaling in dures such as Brust Schiffrin, Perrault [11], Martin [12], or binding energies and alter product http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Applied Electrochemistry Springer Journals

Electrochemical reduction of CO2 at CuAu nanoparticles: size and alloy effects

Loading next page...
 
/lp/springer_journal/electrochemical-reduction-of-co2-at-cuau-nanoparticles-size-and-alloy-E08xuk6JrP
Publisher
Springer Netherlands
Copyright
Copyright © 2018 by Springer Science+Business Media B.V., part of Springer Nature
Subject
Chemistry; Electrochemistry; Physical Chemistry; Industrial Chemistry/Chemical Engineering
ISSN
0021-891X
eISSN
1572-8838
D.O.I.
10.1007/s10800-018-1166-6
Publisher site
See Article on Publisher Site

Abstract

Foil 2nm 6nm O=C=O CO Cu Au Keywords Copper · Gold · Alloy · CO reduction · Electrocatalysis · Carbon dioxide · Nanoparticle 1 Introduction Transition metals such as Cu, Ni, Sn, and Fe have long been Electronic supplementary material The online version of this considered as potential catalysts for CO reduction [1–4]. article (https ://doi.org/10.1007/s1080 0-018-1166-6) contains Of the transition metals, Cu [5–7] has been the most heav- supplementary material, which is available to authorized users. ily investigated as it produces hydrocarbons at relatively −2 * John Flake high current densities (~ 5 mA cm ) and Faradaic efficien- johnflake@lsu.edu cies > 60% [6, 8]. Likewise, other noble metals such as Au and Ag are known to produce CO at relatively high current Cain Department of Chemical Engineering, Louisiana State densities and Faradaic efficiencies exceeding 90% [9 , 10]. University, Baton Rouge, LA 70803, USA Vol.:(0123456789) 1 3 436 Journal of Applied Electrochemistry (2018) 48:435–441 In recent years, there has been significant progress in the follow the same linear relationship as pure metals [28]; so synthesis of well-defined nanoparticles using wet proce - these may offer an opportunity to break the linear scaling in dures such as Brust Schiffrin, Perrault [11], Martin [12], or binding energies and alter product

Journal

Journal of Applied ElectrochemistrySpringer Journals

Published: Feb 19, 2018

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create lists to
organize your research

Export lists, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off