Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Electrochemical determination of 2,4,6-trinitrophenol using a hybrid film composed of a copper-based metal organic framework and electroreduced graphene oxide

Electrochemical determination of 2,4,6-trinitrophenol using a hybrid film composed of a... A metal organic framework (MOF) of the type copper(II)-1,3,5-benzenetricarboxylic acid (Cu-BTC) was electrodeposited on electroreduced graphene oxide (ERGO) placed on a glassy carbon electrode (GCE). The modified GCE was used for highly sensitive electrochemical determination of 2,4,6-trinitrophenol (TNP). The fabrication process of the modified electrode was characterized by scanning electron microscopy and electrochemical impedance spectroscopy. Differential pulse voltammetry (DPV) demonstrates that the Cu-BTC/ERGO/GCE gives stronger signals for TNP reduction than Cu-BTC/GCE or ERGO/GCE alone. DPV also shows TNP to exhibit three reduction peaks, the first at a potential of −0.42 V (vs. SCE). This potential was selected because the other three similarly-structured compounds (2-nitrophenol, 4-nitrophenol, 2,4-dinitrophenol) do not give a signal at this potential. Response is linear in the 0.2 to 10 μM TNP concentration range, with a 0.1 μM detection limit (at S/N = 3) and a 15.98 μA∙μM−1∙cm−2 sensitivity under optimal conditions. The applicability of the sensor was evaluated by detecting TNP in spiked tap water and lake water samples. Recoveries ranged between 95 and 101%. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Microchimica Acta Springer Journals

Electrochemical determination of 2,4,6-trinitrophenol using a hybrid film composed of a copper-based metal organic framework and electroreduced graphene oxide

Download PDF
9 pages

Loading next page...
 
/lp/springer_journal/electrochemical-determination-of-2-4-6-trinitrophenol-using-a-hybrid-RDF3kfPdSC
Publisher
Springer Journals
Copyright
Copyright © 2018 by Springer-Verlag GmbH Austria, part of Springer Nature
Subject
Chemistry; Nanochemistry; Nanotechnology; Characterization and Evaluation of Materials; Analytical Chemistry; Microengineering
ISSN
0026-3672
eISSN
1436-5073
DOI
10.1007/s00604-018-2857-8
Publisher site
See Article on Publisher Site

Abstract

A metal organic framework (MOF) of the type copper(II)-1,3,5-benzenetricarboxylic acid (Cu-BTC) was electrodeposited on electroreduced graphene oxide (ERGO) placed on a glassy carbon electrode (GCE). The modified GCE was used for highly sensitive electrochemical determination of 2,4,6-trinitrophenol (TNP). The fabrication process of the modified electrode was characterized by scanning electron microscopy and electrochemical impedance spectroscopy. Differential pulse voltammetry (DPV) demonstrates that the Cu-BTC/ERGO/GCE gives stronger signals for TNP reduction than Cu-BTC/GCE or ERGO/GCE alone. DPV also shows TNP to exhibit three reduction peaks, the first at a potential of −0.42 V (vs. SCE). This potential was selected because the other three similarly-structured compounds (2-nitrophenol, 4-nitrophenol, 2,4-dinitrophenol) do not give a signal at this potential. Response is linear in the 0.2 to 10 μM TNP concentration range, with a 0.1 μM detection limit (at S/N = 3) and a 15.98 μA∙μM−1∙cm−2 sensitivity under optimal conditions. The applicability of the sensor was evaluated by detecting TNP in spiked tap water and lake water samples. Recoveries ranged between 95 and 101%.

Journal

Microchimica Acta – Springer Journals

Published: Jun 4, 2018

References

  • Chemistry of explosive, second ed
    Akhavan, J
  • Explosive engeneering
    Copper, P
  • A label-free fluorescence sensing approach for selective and sensitive detection of 2,4,6-trinitrophenol (TNP) in aqueous solution using graphitic carbon nitride nanosheets
    Rong, MC; Lin, LP; Song, XH; Zhao, TT; Zhong, YX; Yan, JW; Wang, YR; Chen, X
  • High energy materials: propellants explosives and pyrotechnics
    Agrawal, JP
  • Hand-held femtogram detection of hazardous picric acid with hydrophobic Ag nanopillar SERS substrates and mechanism of elasto-capillarity
    Hakonen, A; Wang, FC; Andersson, PO; Wingfors, H; Rindzevicius, T; Schmidt, MS; Soma, VR; Xu, SC; Li, YQ; Boisen, A; Wu, HA
  • Picric acid hazards
    Cameron, M
  • Molybdenum disulfide quantum dots as a photoluminescence sensing platform for 2,4,6-trinitrophenol detection
    Wang, Y; Ni, YN
  • Analysis of organic components of smokeless gunpowders: high-performance liquidchromatogaphy vs. micellar electrokinetic capillarychromatography
    Cascio, O; Trettene, M; Bortolotti, F; Milana, G; Tagliaro, F
  • Highly-effective liquid chromatographic determination of 2,4,6-trinitrophenol in surface waters after its selective solid phase extraction
    Ivanova, OM; Raks, VA; Zaitsev, VN
  • A comparison of various modes of liquid-liquid based microextraction techniques: determination of picric acid
    Burdel, M; Sandrejova, J; Balogh, IS; Vishnikin, A; Andruch, V
  • Removal, preconcentration and spectrophotometric determination of picric acid in water samples using modified magnetic iron oxide nanoparticles as an efficient adsorbent
    Parham, H; Zargar, B; Rezazadeh, M
  • Sensing of picric acid with a glassy carbon electrode modified with CuS nanoparticles deposited on nitrogen-doped reduced graphene oxide
    Giribabu, K; Oh, SY; Suresh, R; Kumar, SP; Manigandan, R; Munusamy, S; Gnanamoorthy, G; Kim, JY; Huh, YS; Narayanan, V
  • Electroanalysis of some nitro-compounds using bulk bismuth electrode
    Tall, OE; Beh, D; Jaffrezic-Renault, N; Vittori, O
  • Voltammetric determination of environmental pollutant 2,4,6-Trinitrophenol using a bismuth bulk electrode
    Prchal, V; Vyskocil, V; Barek, J
  • Determination of 2,4,6-trinitrophenol by differential pulse voltammetry at a bismuth bulk working electrode
    Jacobsen, M; Duwensee, H; Wachholz, F; Adamovski, M; Flechsig, GU
  • Voltammetric determination of selected nitro compounds at a polished silver solid amalgam composite electrode
    Vyskocil, V; Navratil, T; Danhel, A; Dedik, J; Krejcova, Z; Skvorova, L; Tvrdikova, J; Barek, J
  • Flow injection analysis of picric acid explosive using a copper electrode as electrochemical detector
    Junqueira, JR; Araujo, WR; Salles, MO; Paixao, TR
  • Selective detection of picric acid using functionalized reduced graphene oxide sensor device
    Huang, JR; Wang, LY; Shi, CC; Dai, YJ; Gu, CP; Liu, JH
  • Electrochemical determination of picric acid based on platinum nanoparticles-reduced graphene oxide composite
    Mahyari, M
  • Metal-organic frameworks for heterogeneous basic catalysis
    Zhu, L; Liu, XQ; Jiang, HL; Sun, LB
  • Metal organic frameworks
    James, SL
  • Quantum-chemical characterization of the properties and reactivities of metal-organic frameworks
    Odoh, SO; Cramer, CJ; Truhlar, DG; Gagliardi, L
  • Amperometric determination of reduced glutathione with a new co-based metal-organic coordination polymer modified electrode
    Yuan, BQ; Zhang, RC; Jiao, XX; Li, J; Shi, HZ; Zhang, DJ
  • 3D porous metal-organic framework as an efficient electrocatalyst for nonenzymatic sensing application
    Zhang, DJ; Zhang, JC; Zhang, RC; Shi, HZ; Guo, YY; Guo, XL; Li, SJ; Yuan, BQ
  • Surface assembly of nanometal organic framework on amine functionalized indium tin oxide substrate for impedimetric sensing of parathion
    Deep, A; Bhardwaj, SK; Paul, A; Kim, KH; Kumar, P
  • Porphyrin-based metal-organic framework thin films for electrochemical nitrite detection
    Kung, CW; Chang, TH; Chou, LY; Hupp, JT; Farha, OK; Ho, KC
  • Cu-BTC frameworks-based electrochemical sensing platform for rapid and simple determination of sunset yellow and tartrazine
    Ji, LD; Cheng, Q; Wu, KB; Yang, XF
  • Electroanalytical sensing of Cd2+ based on metal-organic framework modified carbon paste electrode
    Roushani, M; Valipour, A; Saedi, Z
  • Facile synthesis of a Cu-based MOF confined in macroporous carbon hybrid material with enhanced electrocatalytic ability
    Zhang, YF; Bo, XJ; Luhana, C; Wang, H; Li, M; Guo, LP
  • Improved synthesis of graphene oxide
    Marcano, DC; Kosynkin, DV; Berlin, JM; Sinitskii, A; Sun, ZZ; Slesarev, A; Alemany, LB; Lu, W; Tour, JM
  • Fabrication of riboflavin electrochemical sensor based on homoadenine single-stranded DNA/molybdenum disulfide-graphene nanocomposite modified gold electrode
    Wang, Y; Zhaung, QF; Ni, YN
  • Metal organic frameworks/macroporous carbon composites with enhanced stability properties and good electrocatalytic ability for ascorbic acid and hemoglobin
    Zhang, YF; Nsabimana, A; Zhu, LD; Bo, XJ; Han, C; Li, M; Guo, LP
  • A reagentless non-enzymatic hydrogen peroxide sensor presented using electrochemically reduced graphene oxide modified glassy carbon electrode
    Mutyala, S; Mathiyarasu, J
  • The Cu-MOF-199/single-walled carbon nanotubes modified electrode for simultaneous determination of hydroquinone and catechol with extended linear ranges and lower detection limits
    Zhou, J; Li, X; Yang, LL; Yan, SL; Wang, MM; Cheng, D; Chen, Q; Dong, YL; Liu, P; Cai, WQ; Zhang, CC
  • A graphene modified carbon ionic liquid electrode for voltammetric analysis of the sequence of the Staphylococcus aureus nuc gene
    Niu, XL; Chen, W; Wang, XL; Men, YL; Wang, Q; Sun, W; Li, GJ
  • A simple strategy to fabricate high sensitive 2,4-dichlorophenol electrochemical sensor based on metal organic framework Cu3(BTC)2
    Dong, SY; Suo, GC; Li, N; Chen, Z; Peng, L; Fu, YL; Yang, Q; Huang, TL
  • Graphene oxide directed one-step synthesis of flowerlike graphene@HKUST-1 for enzyme-free detection of hydrogen peroxide in biological samples
    Wang, QX; Yang, YZ; Gao, F; Ni, JC; Zhang, YH; Lin, ZY
  • Direct growth of Cu3(BTC)2(H2O)3 · xH2O thin films on modified QCM-gold electrodes -water sorption isotherms
    Biemmi, E; Darga, A; Stock, N; Bein, T
  • One-step synthesis of a copper-based metal-organic framework-graphene nanocomposite with enhanced electrocatalytic activity
    Yang, J; Zhao, FQ; Zeng, BZ
  • Electrochemical hydrogen peroxide sensor based on a glassy carbon electrode modified with nanosheets of copper-doped copper(II) oxide
    Song, HY; Ma, CH; You, LY; Cheng, ZY; Zhang, XH; Yin, BS; Ni, YN; Zhang, KQ
  • Electrochemical oxidation of p-nitrophenol using graphene-modified electrodes, and a comparison to the performance of MWNT-based electrodes
    Arvinte, A; Mahosenaho, M; Pinteala, M; Sesay, A-M; Virtanen, V
  • Electrochemical oxidative determination of 4-nitrophenol based on a glassy carbon electrode modified with a hydroxyapatite nanopowder
    Yin, H; Zhou, Y; Ai, S; Liu, X; Zhu, L; Lu, L
  • Highly fluorescent carbon dots as nanoprobes for sensitive and selective determination of 4-nitrophenol in surface waters
    Ahmed, GHG; Laíño, RB; Calzón, JAG; García, MED