Electrochemical conversion of aqueous ethanol solution in an electrolyzer with a solid polymer electrolyte

Electrochemical conversion of aqueous ethanol solution in an electrolyzer with a solid polymer... The electrochemical conversion of an aqueous ethanol solution (40 vol %) in an electrolysis cell with a solid polymer electrolyte in the presence of various electrocatalysts (Pt, Ir, Ir0.3Ru0.3Sn0.4O2, and Pt0.5Ru0.5) was studied. The electrocatalytic conversion of the ethanol solution at low current densities (up to 0.3 A cm−2) is characterized by a significant (by up to 50%) decrease in the cell voltage relative to water electrolysis. Possible diffusion of ethanol from the anode zone to the cathode zone will not significantly affect operation of the platinum electrocatalyst. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Electrochemical conversion of aqueous ethanol solution in an electrolyzer with a solid polymer electrolyte

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Publisher
Pleiades Publishing
Copyright
Copyright © 2017 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216120260
Publisher site
See Article on Publisher Site

Abstract

The electrochemical conversion of an aqueous ethanol solution (40 vol %) in an electrolysis cell with a solid polymer electrolyte in the presence of various electrocatalysts (Pt, Ir, Ir0.3Ru0.3Sn0.4O2, and Pt0.5Ru0.5) was studied. The electrocatalytic conversion of the ethanol solution at low current densities (up to 0.3 A cm−2) is characterized by a significant (by up to 50%) decrease in the cell voltage relative to water electrolysis. Possible diffusion of ethanol from the anode zone to the cathode zone will not significantly affect operation of the platinum electrocatalyst.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Apr 20, 2017

References

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