The electrochemical conversion of an aqueous ethanol solution (40 vol %) in an electrolysis cell with a solid polymer electrolyte in the presence of various electrocatalysts (Pt, Ir, Ir0.3Ru0.3Sn0.4O2, and Pt0.5Ru0.5) was studied. The electrocatalytic conversion of the ethanol solution at low current densities (up to 0.3 A cm−2) is characterized by a significant (by up to 50%) decrease in the cell voltage relative to water electrolysis. Possible diffusion of ethanol from the anode zone to the cathode zone will not significantly affect operation of the platinum electrocatalyst.
Russian Journal of Applied Chemistry – Springer Journals
Published: Apr 20, 2017
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