Electrochemical behavior of phthaloyl peroxide in aqueous media

Electrochemical behavior of phthaloyl peroxide in aqueous media The electrochemical behavior of phthaloyl peroxide C8H4O4 on an Au disk electrode in a 0.05 M aqueous solution of Na2SO4 was studied by cyclic voltammetry (CVA). It demonstrated a high activity in cathodic reduction with the formation of an irreversible peak on the CVA curve at E =–0.81 V. Additionally, during the anodic oxidation of C8H4O4, the surface of the Au electrode became passivated by compounds which prevented its oxidation during the registration of repeated cycles. Apparently, these compounds are surface complexes of phthaloyl peroxide with a gold cation. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Chemical Bulletin Springer Journals

Electrochemical behavior of phthaloyl peroxide in aqueous media

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Publisher
Springer US
Copyright
Copyright © 2017 by Springer Science+Business Media, LLC, part of Springer Nature
Subject
Chemistry; Chemistry/Food Science, general; Organic Chemistry; Inorganic Chemistry
ISSN
1066-5285
eISSN
1573-9171
D.O.I.
10.1007/s11172-017-1979-1
Publisher site
See Article on Publisher Site

Abstract

The electrochemical behavior of phthaloyl peroxide C8H4O4 on an Au disk electrode in a 0.05 M aqueous solution of Na2SO4 was studied by cyclic voltammetry (CVA). It demonstrated a high activity in cathodic reduction with the formation of an irreversible peak on the CVA curve at E =–0.81 V. Additionally, during the anodic oxidation of C8H4O4, the surface of the Au electrode became passivated by compounds which prevented its oxidation during the registration of repeated cycles. Apparently, these compounds are surface complexes of phthaloyl peroxide with a gold cation.

Journal

Russian Chemical BulletinSpringer Journals

Published: Mar 14, 2018

References

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