Electrochemical behavior of copper(II), zinc(II), tin(II) in joint reduction with thiosulfate ions on a molybdenum electrode from a citrate solution was studied. It was shown that use of sodium citrate salts as a complexing substance makes it possible to diminish the difference between the reduction potentials of the metals in their joint deposition. The results of an analysis of cyclic voltammetric curves were used to develop a method for electrochemical deposition of a Cu–Zn–Sn–S quaternary compound in a single stage from an aqueous solution on a molybdenum electrode at a constant potential.
Russian Journal of Applied Chemistry – Springer Journals
Published: Sep 30, 2015
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