Electrochemical and thermodynamic properties of thulium trichloride in a molten NaCl-KCl-CsCl eutectic

Electrochemical and thermodynamic properties of thulium trichloride in a molten NaCl-KCl-CsCl... Potentiometric method was used to measure the redox potentials of Tm3+/Tm2+ in a eutectic melt of sodium, potassium, and cesium chlorides relative to a chlorine reference electrode in the temperature range 823–973 K. The main thermodynamic characteristics of the redox reaction TmCl2(solution) + 1/2Cl2(g) ⇆ TmCl3(solution) were calculate from the conditional standard potentials $$ E_{{{Tm^{3 + } } \mathord{\left/ {\vphantom {{Tm^{3 + } } {Tm^{2 + } }}} \right. \kern-\nulldelimiterspace} {Tm^{2 + } }}}^* $$ . http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Electrochemical and thermodynamic properties of thulium trichloride in a molten NaCl-KCl-CsCl eutectic

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2010 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427210110091
Publisher site
See Article on Publisher Site

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