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Efficient solvent-free synthesis of tertiary propargylic alcohols from arylacetylenes and ketones promoted by tert-BuOK

Efficient solvent-free synthesis of tertiary propargylic alcohols from arylacetylenes and ketones... A mild and efficient method for the alkynylation of arylacetylenes with ketones promoted by tert -BuOK under solvent-free conditions was developed. The present green synthesis was applicable to many kinds of aromatic and aliphatic ketones providing good to excellent yields of tertiary propargylic alcohols.(Figure not available: see fulltext.) http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Efficient solvent-free synthesis of tertiary propargylic alcohols from arylacetylenes and ketones promoted by tert-BuOK

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References (37)

Publisher
Springer Journals
Copyright
Copyright © 2012 by Springer Science+Business Media B.V.
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
DOI
10.1007/s11164-012-0765-9
Publisher site
See Article on Publisher Site

Abstract

A mild and efficient method for the alkynylation of arylacetylenes with ketones promoted by tert -BuOK under solvent-free conditions was developed. The present green synthesis was applicable to many kinds of aromatic and aliphatic ketones providing good to excellent yields of tertiary propargylic alcohols.(Figure not available: see fulltext.)

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Aug 25, 2012

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