Effects of axial ligands on the intercalation of tetraphenylporphyrinatoantimony(V) into smectite clay layers

Effects of axial ligands on the intercalation of tetraphenylporphyrinatoantimony(V) into smectite... Adsorption and intercalation of +1-charged cationic dihydroxo(tetraphenylporphyrinato)-antimony(V) bromide (1a) into an artificially synthesized smectite clay was investigated. The red shift of the Soret band of 1a was observed in an aqueous clay colloidal solution owing to the adsorption onto the clay. Analyses of the X-ray diffraction of the complex obtained between 1a and the clay indicate the intercalation of 1a into the clay interlayer. The hydroxo group as an axial ligand led to the effective intercalation of 1a into the clay. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Effects of axial ligands on the intercalation of tetraphenylporphyrinatoantimony(V) into smectite clay layers

Loading next page...
 
/lp/springer_journal/effects-of-axial-ligands-on-the-intercalation-of-MA1nHFGQE8
Publisher
Springer Netherlands
Copyright
Copyright © 2007 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856707779160843
Publisher site
See Article on Publisher Site

Abstract

Adsorption and intercalation of +1-charged cationic dihydroxo(tetraphenylporphyrinato)-antimony(V) bromide (1a) into an artificially synthesized smectite clay was investigated. The red shift of the Soret band of 1a was observed in an aqueous clay colloidal solution owing to the adsorption onto the clay. Analyses of the X-ray diffraction of the complex obtained between 1a and the clay indicate the intercalation of 1a into the clay interlayer. The hydroxo group as an axial ligand led to the effective intercalation of 1a into the clay.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 25, 2009

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from Google Scholar, PubMed
Create lists to organize your research
Export lists, citations
Access to DeepDyve database
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off