Effect of the structure and properties of hearth carbon blocks on premature shutdown of electrolytic baths

Effect of the structure and properties of hearth carbon blocks on premature shutdown of... Premature shutdown of electrolytic baths after a short service life leads to an increase in the cost of aluminum and serious economic losses. The most important element governing the service life of an electrolytic bath is the hearth that is lined with refractory hearth blocks. Presence of one concealed crack, that is exposed in the start-up period, may lead to failure of the whole electrolyzer in the first year of service. There are many producers and users of hearth blocks, and there are many specifications for cathode hearth blocks, although the requirements for them are selected in a very empirical way without considering actual service conditions. Scientifically based requirements for the material of hearth blocks is still in the formation stage. In 2004 in four aluminum enterprises under major repair hearth blocks were used from nine different producers that made it possible during evaluation of the statistics for shutting down young baths to determine the effect of the structure and properties of hearth blocks on the service life of electrolyzers and to formulate requirements for hearth block material. The contribution of permeable porous cathode carbon blocks on premature shutdown of electrolyzers by a mechanism of hearth uplift due to formation of a lens of electrolyte and refractory reaction products is demonstrated. Critical gas permeability and the maximum size of permeable pores in refractory hearth units are determined. Applicability of the first and second Hasselman criteria for the heat resistance of hearth block materials is demonstrated for predicting shutdown of young baths by a crack development mechanism in blocks due to thermomechanical stresses. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Refractories and Industrial Ceramics Springer Journals

Effect of the structure and properties of hearth carbon blocks on premature shutdown of electrolytic baths

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Publisher
Springer US
Copyright
Copyright © 2008 by Springer Science+Business Media, Inc.
Subject
Materials Science; Characterization and Evaluation of Materials; Materials Science, general; Ceramics, Glass, Composites, Natural Materials
ISSN
1083-4877
eISSN
1573-9139
D.O.I.
10.1007/s11148-008-9033-3
Publisher site
See Article on Publisher Site

Abstract

Premature shutdown of electrolytic baths after a short service life leads to an increase in the cost of aluminum and serious economic losses. The most important element governing the service life of an electrolytic bath is the hearth that is lined with refractory hearth blocks. Presence of one concealed crack, that is exposed in the start-up period, may lead to failure of the whole electrolyzer in the first year of service. There are many producers and users of hearth blocks, and there are many specifications for cathode hearth blocks, although the requirements for them are selected in a very empirical way without considering actual service conditions. Scientifically based requirements for the material of hearth blocks is still in the formation stage. In 2004 in four aluminum enterprises under major repair hearth blocks were used from nine different producers that made it possible during evaluation of the statistics for shutting down young baths to determine the effect of the structure and properties of hearth blocks on the service life of electrolyzers and to formulate requirements for hearth block material. The contribution of permeable porous cathode carbon blocks on premature shutdown of electrolyzers by a mechanism of hearth uplift due to formation of a lens of electrolyte and refractory reaction products is demonstrated. Critical gas permeability and the maximum size of permeable pores in refractory hearth units are determined. Applicability of the first and second Hasselman criteria for the heat resistance of hearth block materials is demonstrated for predicting shutdown of young baths by a crack development mechanism in blocks due to thermomechanical stresses.

Journal

Refractories and Industrial CeramicsSpringer Journals

Published: Nov 12, 2008

References

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