Effect of the composition of (Mo, Nb, V, Ti)/γ-Al2O3 surface oxide structures on the oxidative dehydrogenation of ethane to ethylene

Effect of the composition of (Mo, Nb, V, Ti)/γ-Al2O3 surface oxide structures on the oxidative... Molecular layering method was used to synthesize on the surface of γ-Al2O3 vanadium-titanium oxide structures of varied composition and structure from the gas phase and niobium- and molybdenum-containing additives from the liquid phase. The resulting composites and the starting aluminum oxide were studied by X-ray diffraction analysis and chemical-analytical and adsorption methods. The catalytic properties of the synthesized products were examined in the oxidative dehydrogenation of ethane. It was shown that the activity of the samples is affected not only by the composition and structure of surface structures, but also by the relative amounts of components in mechanical mixing of vanadium-titanium oxide and niobium oxide supported systems. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Effect of the composition of (Mo, Nb, V, Ti)/γ-Al2O3 surface oxide structures on the oxidative dehydrogenation of ethane to ethylene

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Publisher
Pleiades Publishing
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216010055
Publisher site
See Article on Publisher Site

Abstract

Molecular layering method was used to synthesize on the surface of γ-Al2O3 vanadium-titanium oxide structures of varied composition and structure from the gas phase and niobium- and molybdenum-containing additives from the liquid phase. The resulting composites and the starting aluminum oxide were studied by X-ray diffraction analysis and chemical-analytical and adsorption methods. The catalytic properties of the synthesized products were examined in the oxidative dehydrogenation of ethane. It was shown that the activity of the samples is affected not only by the composition and structure of surface structures, but also by the relative amounts of components in mechanical mixing of vanadium-titanium oxide and niobium oxide supported systems.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: May 19, 2016

References

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