Effect of temperature on thiocarbamide isomerization in concentrated aqueous solutions

Effect of temperature on thiocarbamide isomerization in concentrated aqueous solutions The reaction of isomerization of thiocarbamide to ammonium thiocyanate in aqueous concentrated solutions at temperatures from 100 to 150°C was studied by UV and NMR spectroscopy, as well as by photocolorimetric and conductometric methods. The isomerization reaction rate constants, activation energy, and isomerization ratio were calculated. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Effect of temperature on thiocarbamide isomerization in concentrated aqueous solutions

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2011 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427211060164
Publisher site
See Article on Publisher Site

Abstract

The reaction of isomerization of thiocarbamide to ammonium thiocyanate in aqueous concentrated solutions at temperatures from 100 to 150°C was studied by UV and NMR spectroscopy, as well as by photocolorimetric and conductometric methods. The isomerization reaction rate constants, activation energy, and isomerization ratio were calculated.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jul 16, 2011

References

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