Effect of preparation method on the catalytic performance of Ni/H-ZSM-5 for the reductive deoxygenation of cyclohexanone

Effect of preparation method on the catalytic performance of Ni/H-ZSM-5 for the reductive... The effect of the impregnation and co-precipitation-kneading methods on the catalytic performance of the Ni/H-ZSM-5 catalyst was evaluated via catalytic reductive deoxygenation of cyclohexanone in a fixed bed. The catalysts were characterized by X-ray diffraction, nitrogen adsorption, and NH3-temperature programmed desorption. A sharply acidic and textural change was observed on the catalysts prepared by the different methods, while the metal active phase structure was almost the same. The results of the cyclohexanone reductive deoxygenation reaction indicated that the catalyst based on the co-precipitation-kneading method afforded a higher yield of cyclohexane, and thus proved that the co-precipitation-kneading method is suitable for the preparation of a bi-functional catalyst. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Effect of preparation method on the catalytic performance of Ni/H-ZSM-5 for the reductive deoxygenation of cyclohexanone

Loading next page...
 
/lp/springer_journal/effect-of-preparation-method-on-the-catalytic-performance-of-ni-h-zsm-KDTkxieDVg
Publisher
Springer Netherlands
Copyright
Copyright © 2012 by Springer Science+Business Media B.V.
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-012-0798-0
Publisher site
See Article on Publisher Site

Abstract

The effect of the impregnation and co-precipitation-kneading methods on the catalytic performance of the Ni/H-ZSM-5 catalyst was evaluated via catalytic reductive deoxygenation of cyclohexanone in a fixed bed. The catalysts were characterized by X-ray diffraction, nitrogen adsorption, and NH3-temperature programmed desorption. A sharply acidic and textural change was observed on the catalysts prepared by the different methods, while the metal active phase structure was almost the same. The results of the cyclohexanone reductive deoxygenation reaction indicated that the catalyst based on the co-precipitation-kneading method afforded a higher yield of cyclohexane, and thus proved that the co-precipitation-kneading method is suitable for the preparation of a bi-functional catalyst.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Sep 12, 2012

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from Google Scholar, PubMed
Create lists to organize your research
Export lists, citations
Access to DeepDyve database
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off