Thermodynamic physicochemical modelling and calculation methods are used to study the effect of temperature on phase and chemical transitions in the system MgO-C-Al-Al2OC-Al8B4C7-Al4O4C-Al2O3-Al4C3-H2O-air at 298–2400 K applied to the behavior of carbonized periclase refractories under production and operating conditions. Partial and total pressure, developed by gaseous reaction products of material with an average pore space (CO2, CO, CH4, H2O, H2, etc.) are determined in relation to pressure. The effect of gasification for the carbon component, porosity, original and atmospheric moisture, that is not currently subject to experimental observation, are considered.
Refractories and Industrial Ceramics – Springer Journals
Published: Mar 26, 2007
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