Effect of parameters of state on phase transitions of carbonized periclase refractories

Effect of parameters of state on phase transitions of carbonized periclase refractories Thermodynamic physicochemical modelling and calculation methods are used to study the effect of temperature on phase and chemical transitions in the system MgO-C-Al-Al2OC-Al8B4C7-Al4O4C-Al2O3-Al4C3-H2O-air at 298–2400 K applied to the behavior of carbonized periclase refractories under production and operating conditions. Partial and total pressure, developed by gaseous reaction products of material with an average pore space (CO2, CO, CH4, H2O, H2, etc.) are determined in relation to pressure. The effect of gasification for the carbon component, porosity, original and atmospheric moisture, that is not currently subject to experimental observation, are considered. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Refractories and Industrial Ceramics Springer Journals

Effect of parameters of state on phase transitions of carbonized periclase refractories

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Publisher
Springer US
Copyright
Copyright © 2007 by Springer Science+Business Media, Inc.
Subject
Chemistry; Characterization and Evaluation of Materials; Materials Science; Ceramics, Glass, Composites, Natural Methods
ISSN
1083-4877
eISSN
1573-9139
D.O.I.
10.1007/s11148-007-0096-3
Publisher site
See Article on Publisher Site

Abstract

Thermodynamic physicochemical modelling and calculation methods are used to study the effect of temperature on phase and chemical transitions in the system MgO-C-Al-Al2OC-Al8B4C7-Al4O4C-Al2O3-Al4C3-H2O-air at 298–2400 K applied to the behavior of carbonized periclase refractories under production and operating conditions. Partial and total pressure, developed by gaseous reaction products of material with an average pore space (CO2, CO, CH4, H2O, H2, etc.) are determined in relation to pressure. The effect of gasification for the carbon component, porosity, original and atmospheric moisture, that is not currently subject to experimental observation, are considered.

Journal

Refractories and Industrial CeramicsSpringer Journals

Published: Mar 26, 2007

References

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