Effect of nonstoichiometry of titanium carbide on porous structure of nanoporous carbon produced from the carbide

Effect of nonstoichiometry of titanium carbide on porous structure of nanoporous carbon produced... It was found that the composition of nonstoichiometric titanium carbide in its homogeneity region affects the porous structure parameters of nanoporous carbon produced by thermochemical treatment of titanium carbide with chlorine at 800°C. It is shown that the thermochemical treatment of TiC with stoichiometric composition results in that a monodisperse microporous structure of carbon is formed, whereas a treatment of the same kind of nonstoichiometric titanium carbide TC0.8–0.5 yields a bidisperse micro-mesoporous structure of carbon. The materials obtained are promising, as regards their specific surface area and the type of the porous structure, for application as sorbents and catalyst supports. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Effect of nonstoichiometry of titanium carbide on porous structure of nanoporous carbon produced from the carbide

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427215010048
Publisher site
See Article on Publisher Site

Abstract

It was found that the composition of nonstoichiometric titanium carbide in its homogeneity region affects the porous structure parameters of nanoporous carbon produced by thermochemical treatment of titanium carbide with chlorine at 800°C. It is shown that the thermochemical treatment of TiC with stoichiometric composition results in that a monodisperse microporous structure of carbon is formed, whereas a treatment of the same kind of nonstoichiometric titanium carbide TC0.8–0.5 yields a bidisperse micro-mesoporous structure of carbon. The materials obtained are promising, as regards their specific surface area and the type of the porous structure, for application as sorbents and catalyst supports.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Apr 16, 2015

References

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