Li2Mn4O9 and molybdenum-doped Li2Mn4O9 have been prepared by simple solid-state method. Molybdenum is used as a dopant since it is resistant to both corrosion and high-temperature creep deformation. The structural, morphological, and electrical performances of the samples have been analyzed. The material exhibits a cubic structure with the fd3m space group. Using EDAX, the chemical compositions of the samples have been identified. The dc electrical conductivity of the Mo-doped (LM2) sample is found to be increased to 7.44 × 10−6 S cm−1 at 393 K. The enhanced electrical property of the molybdenum-doped Li2Mn4O9 reveals it as a feasible cathode material for rechargeable Li-ion batteries.
Ionics – Springer Journals
Published: May 27, 2018
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