Effect of molybdenum on Li2Mn4O9 for rechargeable lithium ion batteries

Effect of molybdenum on Li2Mn4O9 for rechargeable lithium ion batteries Li Mn O and molybdenum-doped Li Mn O have been prepared by simple solid-state method. Molybdenum is used as a 2 4 9 2 4 9 dopant since it is resistant to both corrosion and high-temperature creep deformation. The structural, morphological, and electrical performances of the samples have been analyzed. The material exhibits a cubic structure with the fd3m space group. Using EDAX, the chemical compositions of the samples have been identified. The dc electrical conductivity of the Mo-doped (LM2) −6 −1 sample is found to be increased to 7.44 × 10 Scm at 393 K. The enhanced electrical property of the molybdenum-doped Li Mn O reveals it as a feasible cathode material for rechargeable Li-ion batteries. 2 4 9 . . . Keywords Li Mn O Mo-doped Solid-state method Electrical properties 2 4 9 Introduction Li Mn O and Li Mn O remain the most suitable because 4 5 12 2 4 9 of its low cost, less environmental impact, outstanding cyclic Rechargeable Li-ion battery is an excellent energy storage capability, high power, and large cell voltage [3]. Li Mn O 2 4 9 device for the mobile battery cells, automobiles, HEV, and has attractive properties such as http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Ionics Springer Journals

Effect of molybdenum on Li2Mn4O9 for rechargeable lithium ion batteries

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Publisher
Springer Berlin Heidelberg
Copyright
Copyright © 2018 by Springer-Verlag GmbH Germany, part of Springer Nature
Subject
Chemistry; Electrochemistry; Renewable and Green Energy; Optical and Electronic Materials; Condensed Matter Physics; Energy Storage
ISSN
0947-7047
eISSN
1862-0760
D.O.I.
10.1007/s11581-018-2545-z
Publisher site
See Article on Publisher Site

Abstract

Li Mn O and molybdenum-doped Li Mn O have been prepared by simple solid-state method. Molybdenum is used as a 2 4 9 2 4 9 dopant since it is resistant to both corrosion and high-temperature creep deformation. The structural, morphological, and electrical performances of the samples have been analyzed. The material exhibits a cubic structure with the fd3m space group. Using EDAX, the chemical compositions of the samples have been identified. The dc electrical conductivity of the Mo-doped (LM2) −6 −1 sample is found to be increased to 7.44 × 10 Scm at 393 K. The enhanced electrical property of the molybdenum-doped Li Mn O reveals it as a feasible cathode material for rechargeable Li-ion batteries. 2 4 9 . . . Keywords Li Mn O Mo-doped Solid-state method Electrical properties 2 4 9 Introduction Li Mn O and Li Mn O remain the most suitable because 4 5 12 2 4 9 of its low cost, less environmental impact, outstanding cyclic Rechargeable Li-ion battery is an excellent energy storage capability, high power, and large cell voltage [3]. Li Mn O 2 4 9 device for the mobile battery cells, automobiles, HEV, and has attractive properties such as

Journal

IonicsSpringer Journals

Published: May 27, 2018

References

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