Effect of heterometallic biscitratogermanates (-stannates) of Co(II) and Ni(II) on the polycondensation and properties of poly(glycol maleate phthalate) copolymers

Effect of heterometallic biscitratogermanates (-stannates) of Co(II) and Ni(II) on the... The ability of heterometallic Ge(IV) and Sn(IV) complexes [Co(H2O)6][Ge(HCitr)2] (I), [Co(H2O)6] [Sn(HCitr)2] (II), [Ni(H2O)6][Ge(HCitr)2] (III), [Ni(H2O)6][Sn(HCitr)2] (IV), [Mg(H2O)6][Ge(HCitr)2] (V), and [Mg(H2O)6][Sn(HCitr)2] (VI) (H4Citr is citric acid) to activate polycondensation of maleic and phthalic anhydrides with ethylene glycol was studied. Copolymerization of modified poly(glycol maleate phthalate) with triethylene glycol dimethacrylate was performed, and the copolymer characteristics were determined. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Effect of heterometallic biscitratogermanates (-stannates) of Co(II) and Ni(II) on the polycondensation and properties of poly(glycol maleate phthalate) copolymers

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Publisher
Springer Journals
Copyright
Copyright © 2013 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427213040241
Publisher site
See Article on Publisher Site

Abstract

The ability of heterometallic Ge(IV) and Sn(IV) complexes [Co(H2O)6][Ge(HCitr)2] (I), [Co(H2O)6] [Sn(HCitr)2] (II), [Ni(H2O)6][Ge(HCitr)2] (III), [Ni(H2O)6][Sn(HCitr)2] (IV), [Mg(H2O)6][Ge(HCitr)2] (V), and [Mg(H2O)6][Sn(HCitr)2] (VI) (H4Citr is citric acid) to activate polycondensation of maleic and phthalic anhydrides with ethylene glycol was studied. Copolymerization of modified poly(glycol maleate phthalate) with triethylene glycol dimethacrylate was performed, and the copolymer characteristics were determined.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: May 23, 2013

References

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