Effect of H2 in the synthesis of COS using liquid sulfur and CO or CO2 as reactants

Effect of H2 in the synthesis of COS using liquid sulfur and CO or CO2 as reactants The synthesis of COS from CO, CO2 and liquid sulfur in the presence and absence of hydrogen was explored. The reaction of H2 with liquid sulfur produced H2S and polysulfanes, which increase the reactivity of liquid sulfur and provide alternative complementary reaction routes for the formation of COS. The reaction from CO2 proceeds by forming CO as intermediate. Elevated pressure favors formation of COS from both carbon oxides due to the increasing residence time and the saturation of gases in the liquid. Above 350 °C, the solubility of H2S in sulfur and the hydrogenation of COS limit the conversion of CO. The approach provides a highly efficient method for the preparation of COS under mild reaction conditions, without using a catalyst or water adsorbents. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Effect of H2 in the synthesis of COS using liquid sulfur and CO or CO2 as reactants

Loading next page...
 
/lp/springer_journal/effect-of-h2-in-the-synthesis-of-cos-using-liquid-sulfur-and-co-or-co2-yKIenQpCor
Publisher
Springer Netherlands
Copyright
Copyright © 2010 by Springer Science+Business Media B.V.
Subject
Chemistry; Inorganic Chemistry ; Physical Chemistry ; Catalysis
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-010-0131-8
Publisher site
See Article on Publisher Site

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

Monthly Plan

  • Read unlimited articles
  • Personalized recommendations
  • No expiration
  • Print 20 pages per month
  • 20% off on PDF purchases
  • Organize your research
  • Get updates on your journals and topic searches

$49/month

Start Free Trial

14-day Free Trial

Best Deal — 39% off

Annual Plan

  • All the features of the Professional Plan, but for 39% off!
  • Billed annually
  • No expiration
  • For the normal price of 10 articles elsewhere, you get one full year of unlimited access to articles.

$588

$360/year

billed annually
Start Free Trial

14-day Free Trial