Effect of decanethiol on radiation-induced telomerization of tetrafluoroethylene in chlorinated solvents

Effect of decanethiol on radiation-induced telomerization of tetrafluoroethylene in chlorinated... The kinetics of radiation-induced telomerization of tetrafluoroethylene in chlorinated solvents was studied. In the presence of an additionally introduced chain-transfer agent, 1-decanethiol, the soluble telomers are formed more efficiently, and their yield increases. At the ratio tetrafluoroethylene: 1-decanethiol ≤ 2: 1, the completely soluble telomer is formed in the system. By varying the reaction mixture composition, it is possible to control the process and obtain a fully or partially soluble product in a high yield. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Effect of decanethiol on radiation-induced telomerization of tetrafluoroethylene in chlorinated solvents

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Publisher
Pleiades Publishing
Copyright
Copyright © 2014 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427214100085
Publisher site
See Article on Publisher Site

Abstract

The kinetics of radiation-induced telomerization of tetrafluoroethylene in chlorinated solvents was studied. In the presence of an additionally introduced chain-transfer agent, 1-decanethiol, the soluble telomers are formed more efficiently, and their yield increases. At the ratio tetrafluoroethylene: 1-decanethiol ≤ 2: 1, the completely soluble telomer is formed in the system. By varying the reaction mixture composition, it is possible to control the process and obtain a fully or partially soluble product in a high yield.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jan 23, 2015

References

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