Effect of anionic surfactant sodium dodecyl sulfate on the reaction of hexacyanoferrate(III) oxidation of levothyroxine in aqueous medium: a kinetic and mechanistic approach

Effect of anionic surfactant sodium dodecyl sulfate on the reaction of hexacyanoferrate(III)... The effect of anionic surfactant sodium dodecyl sulfate (SDS) on the rate of oxidation of levothyroxine (LVT) by hexacyanoferrate(III) in alkaline medium has been investigated spectrophotometrically at different temperatures. The reaction follows a complex kinetics showing first order dependence of rate with respect to both alkali and LVT. The effect of SDS on the rate of reaction has been observed at the critical miceller concentration of the surfactant. indicating binding of the substrate with the surfactant micelle. The binding parameters have also been evaluated using the Menger and Portnoy model. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Effect of anionic surfactant sodium dodecyl sulfate on the reaction of hexacyanoferrate(III) oxidation of levothyroxine in aqueous medium: a kinetic and mechanistic approach

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Publisher
Springer Netherlands
Copyright
Copyright © 2012 by Springer Science+Business Media B.V.
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-012-0764-x
Publisher site
See Article on Publisher Site

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