Effect of alkali metal oxides on the selectivity of carbon monoxide conversion to give hydrogen on copper-containing catalysts

Effect of alkali metal oxides on the selectivity of carbon monoxide conversion to give hydrogen... Possibility of synthesizing aluminum-zinc-copper catalysts by mechanochemical activation of metallic copper and zinc with ammonium carbonate, followed by introduction of γ-Al2O3 and promoter additives (potassium, rubidium, and cesium carbonates), hydrothermal treatment, and calcination is demonstrated. The effect of the promoter additives and preparation conditions was studied. The activity and selectivity of the samples in the reaction of steam conversion of CO was examined. The composition of by-products formed in the course of a test reaction was determined. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Effect of alkali metal oxides on the selectivity of carbon monoxide conversion to give hydrogen on copper-containing catalysts

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2013 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427213010060
Publisher site
See Article on Publisher Site

Abstract

Possibility of synthesizing aluminum-zinc-copper catalysts by mechanochemical activation of metallic copper and zinc with ammonium carbonate, followed by introduction of γ-Al2O3 and promoter additives (potassium, rubidium, and cesium carbonates), hydrothermal treatment, and calcination is demonstrated. The effect of the promoter additives and preparation conditions was studied. The activity and selectivity of the samples in the reaction of steam conversion of CO was examined. The composition of by-products formed in the course of a test reaction was determined.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Feb 19, 2013

References

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