Early stages of clusters

Early stages of clusters The first stages of growth of small silver clusters are studied using pulse radiolysis. In solutions containing silver ions only, dimmer and trimer silver clusters are observed. The trimer silver cluster can also be observed in solutions containing additional metal ions, such as Zn2+ or Cd2+. During irradiation, the respective monovalent cations are the first intermediates. Zn+ reduces silver by electron transfer, while Cd+ forms first a mixed-metal cluster. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Early stages of clusters

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Publisher
Brill Academic Publishers
Copyright
Copyright © 2001 by VSP 2001
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/15685670152622004
Publisher site
See Article on Publisher Site

Abstract

The first stages of growth of small silver clusters are studied using pulse radiolysis. In solutions containing silver ions only, dimmer and trimer silver clusters are observed. The trimer silver cluster can also be observed in solutions containing additional metal ions, such as Zn2+ or Cd2+. During irradiation, the respective monovalent cations are the first intermediates. Zn+ reduces silver by electron transfer, while Cd+ forms first a mixed-metal cluster.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Oct 7, 2004

References

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