“Dormant” inhibitors of urethane type as controllers of temperature modes of styrene polymerization

“Dormant” inhibitors of urethane type as controllers of temperature modes of styrene... Urethanes based on a series of monoisocyanates and phenolic inhibitors of styrene radical polymerization, which release the initial phenolic inhibitor at elevated temperatures, were prepared and characterized. Some of these compounds meet the requirements to “dormant” inhibitors: they sharply decelerate thermally initiated high-temperature polymerization of styrene and do not noticeably affect the rate of low-temperature polymerization in the presence of an inhibiting substance. The possibility of preventing uncontrollable emergency situations by adding these compounds to the initial monomer was confirmed experimentally. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

“Dormant” inhibitors of urethane type as controllers of temperature modes of styrene polymerization

Loading next page...
 
/lp/springer_journal/dormant-inhibitors-of-urethane-type-as-controllers-of-temperature-446UJomVxC
Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2008 by MAIK Nauka
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427208100224
Publisher site
See Article on Publisher Site

Abstract

Urethanes based on a series of monoisocyanates and phenolic inhibitors of styrene radical polymerization, which release the initial phenolic inhibitor at elevated temperatures, were prepared and characterized. Some of these compounds meet the requirements to “dormant” inhibitors: they sharply decelerate thermally initiated high-temperature polymerization of styrene and do not noticeably affect the rate of low-temperature polymerization in the presence of an inhibiting substance. The possibility of preventing uncontrollable emergency situations by adding these compounds to the initial monomer was confirmed experimentally.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Dec 6, 2008

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from
Google Scholar,
PubMed
Create lists to
organize your research
Export lists, citations
Read DeepDyve articles
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off