The S1−S0 electronic spectrum of methyl cinnamate in a supersonic jet has been investigated to discriminate the transitions of the s-cis/s-trans conformers. Population labelling spectroscopy was applied to the conformer discrimination, and vibronic bands belonging to each conformer were identified. The relative population was estimated from the fluorescence quantum yields obtained by lifetime measurements. It was found that both conformers exist almost equally in a supersonic jet. The conformer identification of the vibronic bands was carried out based on the difference of the red-shift of their hydrogen-bonded complexes with methanol.
Research on Chemical Intermediates – Springer Journals
Published: Apr 15, 2009
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera