Samples of sodium polystyrenesulfonate of molecular weights varying in a 20-fold range were synthesized. The hydrodynamic behavior of the samples was studied in a 0.2 M NaCl solution in which the initial polyelectrolyte effects are suppressed. Relationships between the molecular weight and the translational friction coefficient and intrinsic viscosity were obtained. The theory describing the hydrodynamic behavior of wormlike chains with taking into account both the percolation effects and the excluded-volume effects was applied to estimation of the length of the statistical segment and the cross section of the sodium polystyrenesulfonate molecules in 0.2 M NaCl solution.
Russian Journal of Applied Chemistry – Springer Journals
Published: Oct 26, 2006
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