Development of electrochemical performances of carbon black obtained by the surface organosilicon-modified method

Development of electrochemical performances of carbon black obtained by the surface... Carbon black (CB) was simply modified by tert-butylchlorodimethylsilane (TBDMCl) to form the–C–OSiR and–C–OOSiR structures on the surface of CB. The formation of–C–OSiR and–C–OOSiR structures on CB was verified by FTIR and XRD measurements. The modified carbon black (MCB) has relative high electrochemical performance, which was determined by electrochemical studies. The first charging capacity of MCB is at 343 mAh g–1 and the conductivity of MCB is at 148.1 Sm–1 which is similar to that of CB 155.2 Sm–1. These results indicate that application of the obtained MCB will be promising for lithium anode materials. Meanwhile, these results can also suggest solving the overproduction problem of CB in China. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Development of electrochemical performances of carbon black obtained by the surface organosilicon-modified method

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Publisher
Springer Journals
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216060276
Publisher site
See Article on Publisher Site

Abstract

Carbon black (CB) was simply modified by tert-butylchlorodimethylsilane (TBDMCl) to form the–C–OSiR and–C–OOSiR structures on the surface of CB. The formation of–C–OSiR and–C–OOSiR structures on CB was verified by FTIR and XRD measurements. The modified carbon black (MCB) has relative high electrochemical performance, which was determined by electrochemical studies. The first charging capacity of MCB is at 343 mAh g–1 and the conductivity of MCB is at 148.1 Sm–1 which is similar to that of CB 155.2 Sm–1. These results indicate that application of the obtained MCB will be promising for lithium anode materials. Meanwhile, these results can also suggest solving the overproduction problem of CB in China.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Sep 28, 2016

References

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