Determination of the retention characteristics in thin-layer chromatography taking into account the actual position of the mobile phase front

Determination of the retention characteristics in thin-layer chromatography taking into account... To reveal the actual position of the mobile phase front, corresponding to the free volume of the layer in thin-layer chromatography, it is suggested to use a nonsorbable low-molecular-weight marker. The expressions for the capacity coefficient k′ equilibrium coefficient K d , and corrected R f values (R′f) were obtained taking into account the correction of the position of the mobile phase front. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Determination of the retention characteristics in thin-layer chromatography taking into account the actual position of the mobile phase front

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Publisher
Springer Journals
Copyright
Copyright © 2008 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427208090127
Publisher site
See Article on Publisher Site

Abstract

To reveal the actual position of the mobile phase front, corresponding to the free volume of the layer in thin-layer chromatography, it is suggested to use a nonsorbable low-molecular-weight marker. The expressions for the capacity coefficient k′ equilibrium coefficient K d , and corrected R f values (R′f) were obtained taking into account the correction of the position of the mobile phase front.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Feb 17, 2009

References

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