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Determination of Molecular Structures of Acetone Solutes from Natural Rubber by Pyrolysis Gas Chromatography Coupled to Mass Spectrometry

Determination of Molecular Structures of Acetone Solutes from Natural Rubber by Pyrolysis Gas... Schematic of the preparation and analysis of AS Keywords Natural rubber · Acetone solutes · PyGC–MS as well. In our previous works [15, 16]. Acetone solutes Introduction (AS) were obtained from the standard NR and the effects of AS on the structure and interface interactions of NR/ Natural rubber (NR) as an important strategic commodity silica or NR/CB composites were investigated. The results is used widely in industry, especially in tire manufactur- showed that an appropriate content of holistic AS could ing. Traditionally, the studies on natural rubber compos- enhance the interface interaction between rubber matrix ites filled by carbon black or silica were focused on the and filler significantly inducing an obvious promotion of filler modification [1 –3] or formulation design to promote mechanical or dynamical properties of NR/silica or NR/ the properties of composites. Actually, raw natural rubber CB composites. However, AS is a natural mixture actu- consists of 95 wt% cis-1,4-polyisoprene and 5 wt% non- ally and the specific components in AS that influence the isoprene compounds like carbohydrates, minerals, pro- performance of NR composites significantly had not been teins, phospholipids and acetone solutes [4]. The contents illustrated yet, for which the chemicals or structures of AS and compositions of http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chromatographia Springer Journals

Determination of Molecular Structures of Acetone Solutes from Natural Rubber by Pyrolysis Gas Chromatography Coupled to Mass Spectrometry

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Publisher
Springer Journals
Copyright
Copyright © 2018 by Springer-Verlag GmbH Germany, part of Springer Nature
Subject
Chemistry; Chromatography; Proteomics; Pharmacy; Laboratory Medicine; Analytical Chemistry
ISSN
0009-5893
eISSN
1612-1112
DOI
10.1007/s10337-018-3543-z
Publisher site
See Article on Publisher Site

Abstract

Schematic of the preparation and analysis of AS Keywords Natural rubber · Acetone solutes · PyGC–MS as well. In our previous works [15, 16]. Acetone solutes Introduction (AS) were obtained from the standard NR and the effects of AS on the structure and interface interactions of NR/ Natural rubber (NR) as an important strategic commodity silica or NR/CB composites were investigated. The results is used widely in industry, especially in tire manufactur- showed that an appropriate content of holistic AS could ing. Traditionally, the studies on natural rubber compos- enhance the interface interaction between rubber matrix ites filled by carbon black or silica were focused on the and filler significantly inducing an obvious promotion of filler modification [1 –3] or formulation design to promote mechanical or dynamical properties of NR/silica or NR/ the properties of composites. Actually, raw natural rubber CB composites. However, AS is a natural mixture actu- consists of 95 wt% cis-1,4-polyisoprene and 5 wt% non- ally and the specific components in AS that influence the isoprene compounds like carbohydrates, minerals, pro- performance of NR composites significantly had not been teins, phospholipids and acetone solutes [4]. The contents illustrated yet, for which the chemicals or structures of AS and compositions of

Journal

ChromatographiaSpringer Journals

Published: May 31, 2018

References