Gas-liquid chromatography, chromato-mass-spectrometry, and capillary electrophoresis method were used to study the reaction of deep oxidation of γ-C6H6Cl6 (lindane, an insecticide of contact, enteric, and fumigant action) on molten eutectic mixtures of alkali metal hydroxides and carbonates with and without addition of active components: V2O5, CuO, and NaNO3, in relation to temperature, catalyst load, and O2: γ-C6H6Cl6 molar ratio relative to stoichiometry in a closed system. It is shown that the highest activity, among the catalytic systems studied, in the reaction of deep oxidation of lindane is exhibited by molten catalysts based on a eutectic mixture of alkali metal carbonates with addition of active components, V2O5 and CuO.
Russian Journal of Applied Chemistry – Springer Journals
Published: Jun 28, 2013
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