Deep hexachlorocyclohexane oxidation on molten high-basic catalysts

Deep hexachlorocyclohexane oxidation on molten high-basic catalysts Gas-liquid chromatography, chromato-mass-spectrometry, and capillary electrophoresis method were used to study the reaction of deep oxidation of γ-C6H6Cl6 (lindane, an insecticide of contact, enteric, and fumigant action) on molten eutectic mixtures of alkali metal hydroxides and carbonates with and without addition of active components: V2O5, CuO, and NaNO3, in relation to temperature, catalyst load, and O2: γ-C6H6Cl6 molar ratio relative to stoichiometry in a closed system. It is shown that the highest activity, among the catalytic systems studied, in the reaction of deep oxidation of lindane is exhibited by molten catalysts based on a eutectic mixture of alkali metal carbonates with addition of active components, V2O5 and CuO. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Deep hexachlorocyclohexane oxidation on molten high-basic catalysts

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Publisher
Springer Journals
Copyright
Copyright © 2013 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427213050066
Publisher site
See Article on Publisher Site

Abstract

Gas-liquid chromatography, chromato-mass-spectrometry, and capillary electrophoresis method were used to study the reaction of deep oxidation of γ-C6H6Cl6 (lindane, an insecticide of contact, enteric, and fumigant action) on molten eutectic mixtures of alkali metal hydroxides and carbonates with and without addition of active components: V2O5, CuO, and NaNO3, in relation to temperature, catalyst load, and O2: γ-C6H6Cl6 molar ratio relative to stoichiometry in a closed system. It is shown that the highest activity, among the catalytic systems studied, in the reaction of deep oxidation of lindane is exhibited by molten catalysts based on a eutectic mixture of alkali metal carbonates with addition of active components, V2O5 and CuO.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jun 28, 2013

References

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