Crystallization of CaO–MgO–Al2O3–SiO2 glass prepared by float process

Crystallization of CaO–MgO–Al2O3–SiO2 glass prepared by float process CaO–MgO–Al2O3–SiO2 (CMAS) glass was prepared by float process. The effects of TiO2 and heat-treatment on properties and crystallization behaviors of float glasses were investigated by atomic force microscope, differential scanning calorimeter, X-ray diffraction, electron probe microanalyzer, field emission scanning electron microscope and viscosity test. The results showed that CMAS parent glasses produced by float process had a high surface flatness (Ra is less than 80.1 ± 0.1 nm) and low tin penetration (14 μm). When the concentration of TiO2 increased from 3.51 to 5.01 wt %, the glass transition temperature was decreased, and the crystallization temperature was shifted from 913 to 887°C using differential scanning calorimeter. Field emission scanning electron microscope images showed that phase separation was discovered in CMAS parent glass (containing 3.51 wt % TiO2) treated at 670°C. Diopside as a major crystalline phase was precipitated in CMAS glass-ceramics nucleated at 700°C for 30 min and followed by crystallization at 910°C for 30 min. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Glass Physics and Chemistry Springer Journals

Crystallization of CaO–MgO–Al2O3–SiO2 glass prepared by float process

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Publisher
Pleiades Publishing
Copyright
Copyright © 2017 by Pleiades Publishing, Ltd.
Subject
Materials Science; Ceramics, Glass, Composites, Natural Materials; Characterization and Evaluation of Materials; Materials Science, general; Physical Chemistry
ISSN
1087-6596
eISSN
1608-313X
D.O.I.
10.1134/S1087659617040186
Publisher site
See Article on Publisher Site

Abstract

CaO–MgO–Al2O3–SiO2 (CMAS) glass was prepared by float process. The effects of TiO2 and heat-treatment on properties and crystallization behaviors of float glasses were investigated by atomic force microscope, differential scanning calorimeter, X-ray diffraction, electron probe microanalyzer, field emission scanning electron microscope and viscosity test. The results showed that CMAS parent glasses produced by float process had a high surface flatness (Ra is less than 80.1 ± 0.1 nm) and low tin penetration (14 μm). When the concentration of TiO2 increased from 3.51 to 5.01 wt %, the glass transition temperature was decreased, and the crystallization temperature was shifted from 913 to 887°C using differential scanning calorimeter. Field emission scanning electron microscope images showed that phase separation was discovered in CMAS parent glass (containing 3.51 wt % TiO2) treated at 670°C. Diopside as a major crystalline phase was precipitated in CMAS glass-ceramics nucleated at 700°C for 30 min and followed by crystallization at 910°C for 30 min.

Journal

Glass Physics and ChemistrySpringer Journals

Published: Aug 24, 2017

References

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