Crystal structure of (C2H7N4O)2[UO2(C2O4)2(H2O)]

Crystal structure of (C2H7N4O)2[UO2(C2O4)2(H2O)] The single crystals of (C2H7N4O)2[UO2(C2O4)2(H2O)] were studied by X-ray diffraction. The crystals are monoclinic, space group Pn, Z = 2, unit cell parameters: a = 9.4123(2) Å, b = 8.4591(2) Å, c = 11.8740(3) Å, β = 105.500(10)°, V = 911.02(4) Å3. The main structural units of the crystals of I are islet complex groups [UO2(C2O4)2(H2O)]2− corresponding to the crystal chemical group AB 2 01 M1 (A = UO UO 2 2+ , B01 = C2O 4 2− , M = H2O) of uranyl complexes. Uranium-containing mononuclear complexes are connected into a three-dimensional framework through the electrostatic interactions and hydrogen bonding system involving carbamyolguanidinium ions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Crystal structure of (C2H7N4O)2[UO2(C2O4)2(H2O)]

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406120098
Publisher site
See Article on Publisher Site

Abstract

The single crystals of (C2H7N4O)2[UO2(C2O4)2(H2O)] were studied by X-ray diffraction. The crystals are monoclinic, space group Pn, Z = 2, unit cell parameters: a = 9.4123(2) Å, b = 8.4591(2) Å, c = 11.8740(3) Å, β = 105.500(10)°, V = 911.02(4) Å3. The main structural units of the crystals of I are islet complex groups [UO2(C2O4)2(H2O)]2− corresponding to the crystal chemical group AB 2 01 M1 (A = UO UO 2 2+ , B01 = C2O 4 2− , M = H2O) of uranyl complexes. Uranium-containing mononuclear complexes are connected into a three-dimensional framework through the electrostatic interactions and hydrogen bonding system involving carbamyolguanidinium ions.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Dec 8, 2006

References

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