# Crystal structure and thermodecomposition kinetics of a three-dimensional supramolecular Mn complex with 8-hydroxyquinoline

Crystal structure and thermodecomposition kinetics of a three-dimensional supramolecular Mn... A three-dimensional supramolecular complex, [Mn(8-OHQ)3] · CH3OH (8-OHQ is 8-hydroxyquinoline), C28H22MnN3O4, was synthesized in methanol, and its crystal structure was determined by X-ray crystallography. The crystals are triclinic, space group P $$P\bar 1$$ , a = 10.823(2) Å, b = 13.222(3) Å, c = 17.283(3) Å, α = 90.03(3)°, β = 93.15(3)°, γ = 92.58(3)°, V = 2467.0(8) Å3, Z = 4, F(000) = 1072, ρ = 1.399 g/cm3, μ = 0.575 mm−1. Hydrogen bonds and intermolecular interactions, which are observed in the complex, stabilize its structure. The thermal decomposition kinetics of the complex was investigated under nonisothermal conditions using the Achar differential method and the Coats-Redfern integral method. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

# Crystal structure and thermodecomposition kinetics of a three-dimensional supramolecular Mn complex with 8-hydroxyquinoline

, Volume 32 (7) – Jul 17, 2006
7 pages

/lp/springer_journal/crystal-structure-and-thermodecomposition-kinetics-of-a-three-hlV7Nrok9E
Publisher
Springer Journals
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406070074
Publisher site
See Article on Publisher Site

### Abstract

A three-dimensional supramolecular complex, [Mn(8-OHQ)3] · CH3OH (8-OHQ is 8-hydroxyquinoline), C28H22MnN3O4, was synthesized in methanol, and its crystal structure was determined by X-ray crystallography. The crystals are triclinic, space group P $$P\bar 1$$ , a = 10.823(2) Å, b = 13.222(3) Å, c = 17.283(3) Å, α = 90.03(3)°, β = 93.15(3)°, γ = 92.58(3)°, V = 2467.0(8) Å3, Z = 4, F(000) = 1072, ρ = 1.399 g/cm3, μ = 0.575 mm−1. Hydrogen bonds and intermolecular interactions, which are observed in the complex, stabilize its structure. The thermal decomposition kinetics of the complex was investigated under nonisothermal conditions using the Achar differential method and the Coats-Redfern integral method.

### Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Jul 17, 2006

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