Cross-linking of liquid low-molecular-weight siloxane rubbers with orthotitanic acid esters

Cross-linking of liquid low-molecular-weight siloxane rubbers with orthotitanic acid esters The kinetics of cross-linking of SKTN liquid low-molecular-weight siloxane rubbers with orthotitanic acid esters (tetraethoxytitanium, tetrapropoxytitanium, tetrabutoxytitanium) was studied. The effective rate constants of the cross-linking at 130, 140, 150, and 160°C and the activation energies of the reaction were calculated. The effect of a catalyst, tin phthalocyanine, on the cross-linking of SKTN liquid rubbers with orthotitanic acid esters was examined. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Cross-linking of liquid low-molecular-weight siloxane rubbers with orthotitanic acid esters

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2011 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427211110267
Publisher site
See Article on Publisher Site

Abstract

The kinetics of cross-linking of SKTN liquid low-molecular-weight siloxane rubbers with orthotitanic acid esters (tetraethoxytitanium, tetrapropoxytitanium, tetrabutoxytitanium) was studied. The effective rate constants of the cross-linking at 130, 140, 150, and 160°C and the activation energies of the reaction were calculated. The effect of a catalyst, tin phthalocyanine, on the cross-linking of SKTN liquid rubbers with orthotitanic acid esters was examined.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Dec 25, 2011

References

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