Correct processing of impedance spectra for lead-acid batteries to parameterize the charge-transfer process

Correct processing of impedance spectra for lead-acid batteries to parameterize the... Keywords Electro-chemical impedance spectroscopy · Lead-acid batteries · Test cells · Equivalent electrical circuit modeling · Charge-transfer process · Butler–Volmer equation and contains the ohmic resistance, the charge-transfer 1 Introduction resistance, the double-layer capacitance, and an element representing diffusion processes [6 ]. In the evaluation of The electro-chemical impedance spectroscopy (EIS), parameterized EEC of lead-acid batteries, most attention which contains the complex impedance of the system at is given to the double-layer capacitance and the charge- different frequencies, was already used to analyze lead- transfer resistance, as both correspond to the electro-chem- acid batteries [1–5]. To measure the impedance, the bat- ical charge and discharge process on the surface of the tery is stimulated with a sinusoidal current of a defined electrode [1–5]. frequency and amplitude. Together with the sinusoidal To correctly identify EEC parameters from impedance voltage response, the impedance is calculated. This is spectra, the voltage response has to be generated by a lin- the galvanostatic method to measure the impedance. The ear and time-invariant system (LTI-system) [7] because the potentiostatic method with the voltage as stimulating sig- EEC elements themselves are linear and time-invariant. An nal is possible, too, but the state of charge can drift dur- electro-chemical system is time-variant http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Applied Electrochemistry Springer Journals

Correct processing of impedance spectra for lead-acid batteries to parameterize the charge-transfer process

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Publisher
Springer Netherlands
Copyright
Copyright © 2018 by Springer Science+Business Media B.V., part of Springer Nature
Subject
Chemistry; Electrochemistry; Physical Chemistry; Industrial Chemistry/Chemical Engineering
ISSN
0021-891X
eISSN
1572-8838
D.O.I.
10.1007/s10800-018-1217-z
Publisher site
See Article on Publisher Site

Abstract

Keywords Electro-chemical impedance spectroscopy · Lead-acid batteries · Test cells · Equivalent electrical circuit modeling · Charge-transfer process · Butler–Volmer equation and contains the ohmic resistance, the charge-transfer 1 Introduction resistance, the double-layer capacitance, and an element representing diffusion processes [6 ]. In the evaluation of The electro-chemical impedance spectroscopy (EIS), parameterized EEC of lead-acid batteries, most attention which contains the complex impedance of the system at is given to the double-layer capacitance and the charge- different frequencies, was already used to analyze lead- transfer resistance, as both correspond to the electro-chem- acid batteries [1–5]. To measure the impedance, the bat- ical charge and discharge process on the surface of the tery is stimulated with a sinusoidal current of a defined electrode [1–5]. frequency and amplitude. Together with the sinusoidal To correctly identify EEC parameters from impedance voltage response, the impedance is calculated. This is spectra, the voltage response has to be generated by a lin- the galvanostatic method to measure the impedance. The ear and time-invariant system (LTI-system) [7] because the potentiostatic method with the voltage as stimulating sig- EEC elements themselves are linear and time-invariant. An nal is possible, too, but the state of charge can drift dur- electro-chemical system is time-variant

Journal

Journal of Applied Electrochemistry – Springer Journals

Published: Jun 2, 2018

References

  • Studies of the pulse charge of lead-acid batteries for PV applications: part III. Electrolyte concentration effects on the electrochemical performance of the positive plate
    Kirchev, A
  • Studies of the pulse charge of lead-acid batteries for photovoltaic applications part IV. Pulse charge of the negative plate
    Kirchev, A
  • An in situ generated carbon as integrated conductive additive for hierarchical negative plate of lead-acid battery
    Saravanan, M; Ganesan, M; Ambalavanan, S
  • Voltammetric and electrochemical impedimetric behavior of silica-based gel electrolyte for valve-regulated lead-acid battery
    Gençten, M
  • Characterization of lead(II)-containing activated carbon and its excellent performance of extending lead-acid battery cycle life for high-rate partial-state-of-charge operation
    Tong, P
  • Kinetics of rapid elekctrode reations
    Randles, JEB
  • Impedance spectroscopy. Evgenij Barsoukov
    Macdonald, JR
  • Application of Kramers-Kronig transforms in the analysis of electrochemical impedance data
    Urquidi-Macdonald, M
  • Validation and evaluation of electrochemical impedance spectra of systems with states that change with time
    Schiller, CA
  • A method for improving the robustness of linear Kramers-Kronig validity tests
    Schönleber, M; Klotz, D; Ivers-Tiffée, E
  • Applications of Kramers—Kronig transforms in the analysis of electrochemical impedance data—III. Stability and linearity
    Urquidi-Macdonald, M; Real, S; Macdonald, DD
  • Harmonic analysis for identification of nonlinearities in impedance spectroscopy
    Kiel, M; Bohlen, O; Sauer, DU
  • Zur Theorie der Wasserstoff Überspannung
    Erdey-Grúz, T; Volmer, M
  • Impedance measurements on lead–acid batteries for state-of-charge, state-of-health and cranking capability prognosis in electric and hybrid electric vehicles
    Blanke, H
  • Development of the intelligent charger with battery state-of-health estimation using online impedance spectroscopy
    Nguyen, T-T; Tran, V-L; Choi, W
  • Dynamic modelling of lead/acid batteries using impedance spectroscopy for parameter identification
    Mauracher, P; Karden, E
  • Online impedance spectroscopy of lead acid batteries for storage management of a standalone power plant
    Deperneta, D; Ba, O; Berthonc, A
  • An online battery impedance measurement method using DC–DC power converter control
    Huang, W; Qahouq, JA
  • On the impedance of the gassing reactions in lead-acid batteries
    Hammouche, A
  • Simulation of SLI lead-acid batteries for SoC, aging and cranking capability prediction in automotive applications
    Pilatowicz, G
  • W. A method for measurement and interpretation of impedance spectra for industrial batteries
    Karden, E; Buller, S; Doncker, R
  • Failure mode of valve-regulated lead-acid batteries under high-rate partial-state-of-charge operation
    Lam, LT
  • Influence of measurement procedure on quality of impedance spectra on lead–acid batteries
    Budde-Meiwes, H
  • Convergence properties of the Nelder–Mead simplex method in low dimensions
    Lagarias, JC
  • CPE analysis by local electrochemical impedance spectroscopy
    Jorcin, J-B
  • Electrical battery models
    Witzenhausen, H
  • Lead-acid batteries
    Bode, H
  • Electrochemical systems
    Newman, JS; Thomas-Alyea, KE
  • The electrochemical dissolution of Pb to form PbSO4 by a solution-precipitation mechanism
    Archdale, G; Harrison, JA
  • The electrical double layer and the theory of electrocapillarity
    Grahame, DC
  • Discharge mechanisms and electrochemical impedance spectroscopy measurements of single negative and positive lead-acid battery plates
    D’Alkaine, CV; Mengarda, P; Impinnisi, PR
  • Study of Pb(II) in various H2O–H2SO4 mixtures by differential pulse polarography
    Danel, V; Plichon, V
  • A critical overview of definitions and determination techniques of the internal resistance using lithium-ion, lead-acid, nickel metal-hydride batteries and electrochemical double-layer capacitors as examples
    Piłatowicz, G

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