Copolymers based on products of base hydrolysis of tetraethoxysilane in the presence of poly-N-vinylazoles and polyvinylpyridines

Copolymers based on products of base hydrolysis of tetraethoxysilane in the presence of... The products of base hydrolysis of tetraethoxysilane in the presence of polymeric nitrogen bases poly-1-vinylpyrazole, poly-1-vinylimidazole, poly-4-vinylpyridine, and poly-2-methyl-5-vinylpyridine were isolated. The conditions of their formation, chemical composition, structural characteristics, and sorption properties with respect to noble metals (Ag, Au, Pt, and Pd) were studied. These products are highly dispersed thermally stable interpenetrating copolymers poorly soluble in water and organic solvents. Their composition and properties are governed by the kind of the polymeric nitrogen base. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Copolymers based on products of base hydrolysis of tetraethoxysilane in the presence of poly-N-vinylazoles and polyvinylpyridines

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2007 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427207080241
Publisher site
See Article on Publisher Site

Abstract

The products of base hydrolysis of tetraethoxysilane in the presence of polymeric nitrogen bases poly-1-vinylpyrazole, poly-1-vinylimidazole, poly-4-vinylpyridine, and poly-2-methyl-5-vinylpyridine were isolated. The conditions of their formation, chemical composition, structural characteristics, and sorption properties with respect to noble metals (Ag, Au, Pt, and Pd) were studied. These products are highly dispersed thermally stable interpenetrating copolymers poorly soluble in water and organic solvents. Their composition and properties are governed by the kind of the polymeric nitrogen base.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Sep 28, 2007

References

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