Copolymerization of Chlorine-Substituted Monoisocyanates with ε-Caprolactone in the Presence of Sodium Caprolactamate

Copolymerization of Chlorine-Substituted Monoisocyanates with ε-Caprolactone in the Presence of... Copolymerization of ε-caprolactone with a series of aromatic chlorine-substituted monoisocyanates in the presence of catalytic amounts of sodium caprolactamate was performed. The structures of the products obtained and their macromolecular characteristics were determined by IR and 1H NMR spectroscopy and by gel permeation chromatography; kinetic and thermodynamic relationships of the process were found. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Copolymerization of Chlorine-Substituted Monoisocyanates with ε-Caprolactone in the Presence of Sodium Caprolactamate

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2005 by MAIK "Nauka/Interperiodica"
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1007/s11167-005-0628-x
Publisher site
See Article on Publisher Site

Abstract

Copolymerization of ε-caprolactone with a series of aromatic chlorine-substituted monoisocyanates in the presence of catalytic amounts of sodium caprolactamate was performed. The structures of the products obtained and their macromolecular characteristics were determined by IR and 1H NMR spectroscopy and by gel permeation chromatography; kinetic and thermodynamic relationships of the process were found.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Dec 30, 2005

References

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