Coordination polymer of Ag trifluoroacetate with 2-methylpyrazine: Synthesis and structure of [Ag(CF3CO2)(2-Me-Pyz)]

Coordination polymer of Ag trifluoroacetate with 2-methylpyrazine: Synthesis and structure of... The [Ag(CF3CO2)(2-Me-Pyz)] complex (where 2-Me-Pyz is 2-methylpyrazine) was synthesized and its structure was determined. The crystals are monoclinic, space group P21/n, a = 12.440(2) Å, b = 2.605(3) Å, c = 12.646(3) Å, β = 95.95(3)°, V = 1972.3(7) Å3, ρ = 2.122 g/cm3, Z = 8. The structure consists of the polymer zigzag chains of [Ag(C5H6N2)] − ∞ united into a three-dimensional framework through (CF3CO2)− anions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Coordination polymer of Ag trifluoroacetate with 2-methylpyrazine: Synthesis and structure of [Ag(CF3CO2)(2-Me-Pyz)]

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Publisher
Springer Journals
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406110017
Publisher site
See Article on Publisher Site

Abstract

The [Ag(CF3CO2)(2-Me-Pyz)] complex (where 2-Me-Pyz is 2-methylpyrazine) was synthesized and its structure was determined. The crystals are monoclinic, space group P21/n, a = 12.440(2) Å, b = 2.605(3) Å, c = 12.646(3) Å, β = 95.95(3)°, V = 1972.3(7) Å3, ρ = 2.122 g/cm3, Z = 8. The structure consists of the polymer zigzag chains of [Ag(C5H6N2)] − ∞ united into a three-dimensional framework through (CF3CO2)− anions.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Nov 6, 2006

References

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