Coordination polyhedra LnOn (Ln = Er, Tm, Yb, Lu) in crystal structures

Coordination polyhedra LnOn (Ln = Er, Tm, Yb, Lu) in crystal structures The Voronoi-Dirichlet polyhedra (VDP) and the method of intersecting spheres were used to analyze crystal structures of 728 compounds containing 976 crystallographically non-equivalent sorts of LnOn polyhedra (Ln = Er, Tm, Yb, Lu). The Ln C.N. vary from 3 to 10, and 14 sorts of coordination polyhedra are present in the structures. Despite the great diversity of C.N., the volume of the VDP was found to depend only on the nature of the Ln atom and its valence state. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Coordination polyhedra LnOn (Ln = Er, Tm, Yb, Lu) in crystal structures

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S107032840601009X
Publisher site
See Article on Publisher Site

Abstract

The Voronoi-Dirichlet polyhedra (VDP) and the method of intersecting spheres were used to analyze crystal structures of 728 compounds containing 976 crystallographically non-equivalent sorts of LnOn polyhedra (Ln = Er, Tm, Yb, Lu). The Ln C.N. vary from 3 to 10, and 14 sorts of coordination polyhedra are present in the structures. Despite the great diversity of C.N., the volume of the VDP was found to depend only on the nature of the Ln atom and its valence state.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Feb 13, 2006

References

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