ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2006, Vol. 32, No. 12, pp. 849–857. © Pleiades Publishing, Inc., 2006. Original Russian Text © S.P. Gubin, N.A. Kataeva, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 12, pp. 883–893. S. P. Gubin and N. A. Kataeva Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia Received December 21, 2005 DOI: 10.1134/S1070328406120013 The coordination chemistry of nanoparticles is a new gold in the mid-19th century, thus laying the ground- area of investigations in modern chemistry. Nanoparti- work for the modern science of colloids . cles are giant pseudomolecules with complex internal It turned out that potential ligands can substantially structures. They mostly consist of the core and the shell inﬂuence not only the optical characteristics of nano- and often contain surface functional groups. They are particles but also their solubilities and stabilities in quasizero-dimensional (0D) nanoentities; all their char- solutions. This aroused interest in the coordination acteristic linear dimensions are of the same order of mag- chemistry of nanoparticles. nitude (usually, no larger than 30 nm). Nanoparticles are Classic coordination chemistry studies quite a deﬁ- mostly spheroidal to minimize the potential energy.
Russian Journal of Coordination Chemistry – Springer Journals
Published: Dec 8, 2006
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