Access the full text.
Sign up today, get DeepDyve free for 14 days.
S. Aguado, J. Canivet, Y. Schuurman, D. Farrusseng (2011)
Tuning the activity by controlling the wettability of MOF eggshell catalysts: A quantitative structure–activity studyJournal of Catalysis, 284
B. Melde, B. Holland, C. Blanford, A. Stein (1999)
Mesoporous sieves with unified hybrid inorganic/organic frameworksChemistry of Materials, 11
A. Sayari, S. Hamoudi, Yong Yang, A. Moudrakovski, John Ripmeester (2000)
New insights into the synthesis, morphology, and growth of periodic mesoporous organosilicasChemistry of Materials, 12
T. Gill, K. Mann (1982)
Photochemical properties of the cyclopentadienyl(.eta.6-benzene)ruthenium(II) cation. The synthesis and reactions of a synthetically useful intermediate: the cyclopentadienyltris(acetonitrile)ruthenium(II) cationOrganometallics, 1
Tewodros Asefa, M. MacLachlan, N. Coombs, G. Ozin (1999)
Periodic mesoporous organosilicas with organic groups inside the channel wallsNature, 402
T. Tani, Norihiro Mizoshita, S. Inagaki (2009)
Luminescent periodic mesoporous organosilicasJournal of Materials Chemistry, 19
S. Fujita, S. Inagaki (2008)
Self-Organization of Organosilica Solids with Molecular-Scale and Mesoscale Periodicities†Chemistry of Materials, 20
E. Karslyan, D. Perekalin, P. Petrovskii, K. Lyssenko, A. Kudinov (2008)
Thermal arene exchange in the naphthalene complex [CpRu(η6-C10H8)]+Russian Chemical Bulletin, 57
D. Perekalin, E. Karslyan, P. Petrovskii, A. Borissova, K. Lyssenko, A. Kudinov (2012)
Arene Exchange in the Ruthenium–Naphthalene Complex [CpRu(C10H8)]+European Journal of Inorganic Chemistry, 2012
A. Mcnair, J. Schrenk, K. Mann (1984)
Effect of arene substituents and temperature on the arene replacement reactions of [(η5-C5H5)Fe(η6-arene)]+ and [(η5-C5H5)Ru(η6-arene)]+Inorganic Chemistry, 23
Yong Yang, A. Sayari (2008)
Mesoporous Organosilicates from Multiple Precursors: Co-Condensation or Phase Segregation/Separation?Chemistry of Materials, 20
F. Grepioni, G. Cojazzi, D. Braga, E. Marseglia, L. Scaccianoce, B. Johnson (1999)
Crystal architecture of the cocrystalline salt [Ru(η5-C5H5)(η6-trans-PhCHCHPh)][PF6]·0.5trans-PhCHCHPh and the reversible order–disorder phase transition in [Ru(η5-C5H5)(η6-C6H6)][PF6]Journal of The Chemical Society-dalton Transactions
M. Ohashi, M. Kapoor, S. Inagaki (2008)
Chemical modification of crystal-like mesoporous phenylene-silica with amino group.Chemical communications, 7
Joseph Nguyen, Seth Cohen (2010)
Moisture-resistant and superhydrophobic metal-organic frameworks obtained via postsynthetic modification.Journal of the American Chemical Society, 132 13
R. Voss, Arne Thomas, M. Antonietti, G. Ozin (2005)
Synthesis and characterization of highly amine functionalized mesoporous organosilicas by an “all-in-one” approachJournal of Materials Chemistry, 15
Y. Nakajima, Hiroharu Suzuki (2003)
Nitrogen−Nitrogen Bond Cleavage of Hydrazine Derivatives by a Trinuclear Pentahydride Complex of Ruthenium, (Cp‘Ru)3(μ-H)3(μ3-H)2 (Cp‘ = η5-C5Me5)Organometallics, 22
M. Kapoor, Qihua Yang, S. Inagaki (2002)
Self-assembly of biphenylene-bridged hybrid mesoporous solid with molecular-scale periodicity in the pore walls.Journal of the American Chemical Society, 124 51
S. Inagaki, S. Guan, T. Ohsuna, O. Terasaki (2002)
An ordered mesoporous organosilica hybrid material with a crystal-like wall structureNature, 416
A. Stein, B. Melde, R. Schroden (2000)
Hybrid Inorganic–Organic Mesoporous Silicates—Nanoscopic Reactors Coming of AgeAdvanced Materials, 12
R. Zelonka, M. Baird (1972)
Reactions of π-benzeneruthenium(II) complexes with alkylating reagentsJournal of Organometallic Chemistry, 44
M. Matsuoka, T. Kamegawa, Tae-Ho Kim, Takahiro Sakai, M. Anpo (2010)
Incorporation of arene metal carbonyl complexes within inorganic-organic hybrid mesoporous materials by CVD method.Journal of nanoscience and nanotechnology, 10 1
T. Kamegawa, Masakazu Saito, Tetsuji Watanabe, Kazuhiro Uchihara, M. Kondo, M. Matsuoka, M. Anpo (2011)
Preparation of inorganic–organic hybrid mesoporous material incorporating organoruthenium complexes (–[C6H4RuCp]PF6–) and its application as a heterogeneous catalystJournal of Materials Chemistry, 21
A. Mcnair, J. Schrenk, K. Mann (1984)
Effect of arene substituents and temperature on the arene replacement reactions of ((eta/sup 5/-C/sub 5/H/sub 5/)Fe(eta/sup 6/-arene))/sup +/ and ((eta/sup 5/-C/sub 5/H/sub 5/)Ru(eta/sup 6/-arene))/sup +/Inorganic Chemistry
F. Hoffmann, M. Cornelius, J. Morell, M. Fröba (2006)
Silica-based mesoporous organic-inorganic hybrid materials.Angewandte Chemie, 45 20
S. Inagaki, O. Ohtani, Y. Goto, Kentaro Okamoto, M. Ikai, K. Yamanaka, T. Tani, T. Okada (2009)
Light harvesting by a periodic mesoporous organosilica chromophore.Angewandte Chemie, 48 22
Qihua Yang, Jian Liu, Jie Yang, M. Kapoor, S. Inagaki, Can Li (2004)
Synthesis; characterization; and catalytic activity of sulfonic acid-functionalized periodic mesoporous organosilicasJournal of Catalysis, 228
T. Kamegawa, Takahiro Sakai, M. Matsuoka, M. Anpo (2005)
Preparation and characterization of unique inorganic-organic hybrid mesoporous materials incorporating arenetricarbonyl complexes [-C6H4M(CO)3-] (M = Cr, Mo).Journal of the American Chemical Society, 127 48
K. Nakajima, I. Tomita, M. Hara, S. Hayashi, K. Domen, J. Kondo (2005)
A Stable and Highly Active Hybrid Mesoporous Solid Acid CatalystAdvanced Materials, 17
M. Cornelius, F. Hoffmann, M. Fröba (2005)
Periodic Mesoporous Organosilicas with a Bifunctional Conjugated Organic Unit and Crystal-like Pore WallsChemistry of Materials, 17
S. Inagaki, S. Guan, Y. Fukushima, T. Ohsuna, O. Terasaki (1999)
Novel Mesoporous Materials with a Uniform Distribution of Organic Groups and Inorganic Oxide in Their FrameworksJournal of the American Chemical Society, 121
Chiaki Yoshina-Ishii, Tewodros Asefa, N. Coombs, M. MacLachlan, G. Ozin (1999)
Periodic mesoporous organosilicas, PMOs: fusion of organic and inorganic chemistry ‘inside’ the channel walls of hexagonal mesoporous silicaChemical Communications
An organoruthenium complex (–[biphRuCp]PF6–; biph = –(C6H4)2–, Cp = C5H5), constructed within a biphenylene-bridged inorganic–organic hybrid mesoporous material (HMM–biph) by use of a simple ligand-exchange reaction, has been used as a heterogeneous catalyst. UV–visible and X-ray absorption fine structure (XAFS) studies furnished evidence that the structure of the complex is closely similar to that of [(C6H6)RuCp]PF6, suggesting that the biphenylene moiety within HMM–biph directly coordinates the metal center of the organoruthenium complex. The –[biphRuCp]PF6– complex constructed within the HMM–biph (HMM–biphRuCp) catalyzes hydrosilylation of 1-hexyne with triethylsilane in a solid–gas heterogeneous system and gives α-vinylsilane as a main product. Moreover, HMM–biphRuCp has higher catalytic activity than the –[phRuCp]PF6– (ph = –C6H4–) complex constructed within phenylene-bridged HMM (HMM–phRuCp). The high catalytic performance of HMM–biphRuCp can be attributed to the high loading of the HMM–biph with the Ru complex, because of the electron-donating ability of the biphenylene moieties.
Research on Chemical Intermediates – Springer Journals
Published: Oct 30, 2013
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.