Construction of a new Ho3+ PVC-membrane electrochemical sensor based on N,N′-dipyridoxyl(1,4-butanediamine)

Construction of a new Ho3+ PVC-membrane electrochemical sensor based on... N,N′-dipyridoxyl(1, 4-butanediamine) (PYBA) (2 wt % ), nitrobenzene (66 wt %), sodium tetra phenyl borate (2 wt ), and poly vinyl chloride (30 wt %) were applied to create a PVC membrane in Ho3+ selective electrode (Ho-SE). Over the concentration range of 1.0 × 10‒5 to 1.0 × 10‒2 M in holmium(III) solution a linear response with lower detection of limit equal 4.0 × 10‒6 M was exhibited by new holmium(III) sensor. Ho-SE possessed a Nernstian slope of 20.1 ± 0.8 mV decade‒1 in very short time spans (~9 s). The potential response of electrode remains without any changes over a pH range of 2.77–8.71. The selectivity coefficient data which was considered by matched potential method for variety of common cations indicated no significant interference. An acceptable recovery for Ho3+ in the blend of several cations has been achieved. The utility of Ho-SE in potentiometric titration as an end point indicator electrode gave successfully results. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Construction of a new Ho3+ PVC-membrane electrochemical sensor based on N,N′-dipyridoxyl(1,4-butanediamine)

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Publisher
Springer Journals
Copyright
Copyright © 2017 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216120119
Publisher site
See Article on Publisher Site

Abstract

N,N′-dipyridoxyl(1, 4-butanediamine) (PYBA) (2 wt % ), nitrobenzene (66 wt %), sodium tetra phenyl borate (2 wt ), and poly vinyl chloride (30 wt %) were applied to create a PVC membrane in Ho3+ selective electrode (Ho-SE). Over the concentration range of 1.0 × 10‒5 to 1.0 × 10‒2 M in holmium(III) solution a linear response with lower detection of limit equal 4.0 × 10‒6 M was exhibited by new holmium(III) sensor. Ho-SE possessed a Nernstian slope of 20.1 ± 0.8 mV decade‒1 in very short time spans (~9 s). The potential response of electrode remains without any changes over a pH range of 2.77–8.71. The selectivity coefficient data which was considered by matched potential method for variety of common cations indicated no significant interference. An acceptable recovery for Ho3+ in the blend of several cations has been achieved. The utility of Ho-SE in potentiometric titration as an end point indicator electrode gave successfully results.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Apr 20, 2017

References

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