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Concentration effects in homopolymerization of amine- and amide-containing (meth)acrylic monomers in organic solvents

Concentration effects in homopolymerization of amine- and amide-containing (meth)acrylic monomers... The dependences of the initial reduced rate of radical homopolymerization on the initial concentration of the monomers were studied for toluene and dimethylformamide solutions of four amine-containing (meth)acrylic esters and amides, and also for N-(n-butyl)acrylamide and n-butyl methacrylate taken for comparison. The concentration effects are similar for all the methacrylic monomers and are specific in the case of acrylamides {N-(n-butyl)acrylamide and N-[3-(dimethylamino)propyl]acrylamide}, which is associated with the specific features of the structure of the prereaction monomeric associates. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Concentration effects in homopolymerization of amine- and amide-containing (meth)acrylic monomers in organic solvents

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References (23)

Publisher
Springer Journals
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
DOI
10.1134/S1070427215060221
Publisher site
See Article on Publisher Site

Abstract

The dependences of the initial reduced rate of radical homopolymerization on the initial concentration of the monomers were studied for toluene and dimethylformamide solutions of four amine-containing (meth)acrylic esters and amides, and also for N-(n-butyl)acrylamide and n-butyl methacrylate taken for comparison. The concentration effects are similar for all the methacrylic monomers and are specific in the case of acrylamides {N-(n-butyl)acrylamide and N-[3-(dimethylamino)propyl]acrylamide}, which is associated with the specific features of the structure of the prereaction monomeric associates.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Sep 30, 2015

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